化工进展
化工進展
화공진전
CHEMICAL INDUSTRY AND ENGINEERING PROGRESS
2012年
9期
2075-2083
,共9页
张兵兵%王慧敏%曾尚红%苏海全
張兵兵%王慧敏%曾尚紅%囌海全
장병병%왕혜민%증상홍%소해전
二氧化碳%矿物封存%直接碳化%间接碳化
二氧化碳%礦物封存%直接碳化%間接碳化
이양화탄%광물봉존%직접탄화%간접탄화
carbon dioxide%mineral carbonation%direct carbonation%indirect carbonation
面对温室效应带来的生态灾难,利用各种技术封存固定CO2成为了关键,CO2矿物封存是其中最环保、最安全、最永恒的CO2固定方式。本文从封存方案、反应机理及碳化原料三方面详细介绍了CO2矿物封存技术的基本原理,并全面概述了CO2矿物封存的技术路线,其中包括直接碳化路线以及以酸浸出工艺、熔盐碳化工艺、铵盐浸出工艺以及生物浸出工艺为代表的间接碳化路线。同时结合国内外研究进展分析了各种CO2矿物封存技术的优缺点及其产业化前景,并提出今后我国CO2矿物封存技术研究和发展应更加注重从资源综合利用的角度考虑,将CO2看做是廉价碳资源材料,积极推进碳捕获、利用与封存项目的实施。
麵對溫室效應帶來的生態災難,利用各種技術封存固定CO2成為瞭關鍵,CO2礦物封存是其中最環保、最安全、最永恆的CO2固定方式。本文從封存方案、反應機理及碳化原料三方麵詳細介紹瞭CO2礦物封存技術的基本原理,併全麵概述瞭CO2礦物封存的技術路線,其中包括直接碳化路線以及以痠浸齣工藝、鎔鹽碳化工藝、銨鹽浸齣工藝以及生物浸齣工藝為代錶的間接碳化路線。同時結閤國內外研究進展分析瞭各種CO2礦物封存技術的優缺點及其產業化前景,併提齣今後我國CO2礦物封存技術研究和髮展應更加註重從資源綜閤利用的角度攷慮,將CO2看做是廉價碳資源材料,積極推進碳捕穫、利用與封存項目的實施。
면대온실효응대래적생태재난,이용각충기술봉존고정CO2성위료관건,CO2광물봉존시기중최배보、최안전、최영항적CO2고정방식。본문종봉존방안、반응궤리급탄화원료삼방면상세개소료CO2광물봉존기술적기본원리,병전면개술료CO2광물봉존적기술로선,기중포괄직접탄화로선이급이산침출공예、용염탄화공예、안염침출공예이급생물침출공예위대표적간접탄화로선。동시결합국내외연구진전분석료각충CO2광물봉존기술적우결점급기산업화전경,병제출금후아국CO2광물봉존기술연구화발전응경가주중종자원종합이용적각도고필,장CO2간주시렴개탄자원재료,적겁추진탄포획、이용여봉존항목적실시。
Facing the ecological disaster caused by greenhouse effect,the key is to seal the huge carbon dioxide using various CO2 storage technologies.Carbon dioxide mineral sequestration is one of the most environment-friendly,secure and permanent technology.This paper introduces the basic principle of CO2 mineral carbonation in terms of sequestration solutions,reaction kinetics and carbonation materials,and various process routes of CO2 mineral carbonation are described,including direct mineral carbonation and indirect mineral carbonation,such as acid extraction,molten salt process,ammonia extraction and bioleaching.Meanwhile,combined with the research and development of CO2 mineral carbonation techniques both in China and the rest of the world,the advantages and disadvantages of present researches and commercialization prospect are also discussed.Moreover,it is proposed that the next key point of research and development of CO2mineral carbonation techniques is to pay more attention to resources utilization,regarding CO2 as cheap carbon source,and promoting carbon capture,utilization and sequestration(CCUS) project.