化工进展
化工進展
화공진전
CHEMICAL INDUSTRY AND ENGINEERING PROGRESS
2012年
12期
2672-2677
,共6页
刘宗宽%张磊%江健%边城
劉宗寬%張磊%江健%邊城
류종관%장뢰%강건%변성
加氢精制和加氢裂化催化剂%金属-载体之间的相互作用%煤焦油%载体%助剂%活性金属
加氫精製和加氫裂化催化劑%金屬-載體之間的相互作用%煤焦油%載體%助劑%活性金屬
가경정제화가경열화최화제%금속-재체지간적상호작용%매초유%재체%조제%활성금속
hydro-fining and hydro-cracking catalyst%metal-support interaction%coal tar%carrier%promoter%active metal
阐述了催化剂中活性金属和助剂的种类及含量对催化剂性能的影响;总结了活性金属和助剂对金属-载体相互作用、催化剂酸分布以及催化剂表面性质的影响机制。指出制备一个性能优良的催化剂应从两方面入手,首先是制备一个性能优良的载体,要求它具有合适的孔分布和酸分布,负载的金属应具有较高的分散度和还原性能。探讨了适于煤焦油的加氢处理催化剂,主要是防止催化剂的中毒、积炭、失活,并且协调各种催化剂同步失活,以利于整个装置运行周期的延长。旨在为煤焦油加氢精制和加氢裂化催化剂研究(设计)提供一定的理论指导,避免焦油加氢精制和加氢裂化催化剂研究和开发的盲目性。
闡述瞭催化劑中活性金屬和助劑的種類及含量對催化劑性能的影響;總結瞭活性金屬和助劑對金屬-載體相互作用、催化劑痠分佈以及催化劑錶麵性質的影響機製。指齣製備一箇性能優良的催化劑應從兩方麵入手,首先是製備一箇性能優良的載體,要求它具有閤適的孔分佈和痠分佈,負載的金屬應具有較高的分散度和還原性能。探討瞭適于煤焦油的加氫處理催化劑,主要是防止催化劑的中毒、積炭、失活,併且協調各種催化劑同步失活,以利于整箇裝置運行週期的延長。旨在為煤焦油加氫精製和加氫裂化催化劑研究(設計)提供一定的理論指導,避免焦油加氫精製和加氫裂化催化劑研究和開髮的盲目性。
천술료최화제중활성금속화조제적충류급함량대최화제성능적영향;총결료활성금속화조제대금속-재체상호작용、최화제산분포이급최화제표면성질적영향궤제。지출제비일개성능우량적최화제응종량방면입수,수선시제비일개성능우량적재체,요구타구유합괄적공분포화산분포,부재적금속응구유교고적분산도화환원성능。탐토료괄우매초유적가경처리최화제,주요시방지최화제적중독、적탄、실활,병차협조각충최화제동보실활,이리우정개장치운행주기적연장。지재위매초유가경정제화가경열화최화제연구(설계)제공일정적이론지도,피면초유가경정제화가경열화최화제연구화개발적맹목성。
This paper described the influences of the type and content of active metal and promoter in catalytic performances,and summarized the regulating mechanisms of active metal and promoter on the catalyst’s metal-carrier interaction,acids distribution and surface properties.To prepare a catalyst with good performance,two aspects should be considered,i.e.an excellent carrier with proper pores distribution and acids distribution,and a loaded active metal with high dispersion degree and outstanding reduction performance.We discussed the suitable hydrotreating catalyst for coal tar,mainly focusing on preventing catalyst poisoning,carbon deposit,and deactivation,as well as inactivating the hydrotreating catalysts synchronously in order to prolong the operation cycle of entire unit.The paper aims at providing some theoretical guidance for the research(design) of coal tar hydro-refining and hydrocracking catalysts so as to avoid the research and development blindness.