化工技术与开发
化工技術與開髮
화공기술여개발
TECHNOLOGY & DVELOPMENT OF CHEMICAL INDUSTRY
2014年
2期
4-7
,共4页
陈刚%李小龙%苏慧君%张洁%赵景瑞%唐德尧
陳剛%李小龍%囌慧君%張潔%趙景瑞%唐德堯
진강%리소룡%소혜군%장길%조경서%당덕요
多胺酰胺%降凝%降粘
多胺酰胺%降凝%降粘
다알선알%강응%강점
polyamine amide%pour point depression%viscosity reduction
以脂肪酸和多胺为原料合成多胺酰胺,用三聚甲醛进一步交联多胺酰胺,将其作为稠油流动性改进剂,评价了其对稠油凝点和粘度的影响。结果表明,三聚甲醛交联的多胺酰胺型稠油流动性改进剂有一定的降凝作用,最高为2.2℃。三聚甲醛交联的多胺酰胺型稠油流动性改进剂中脂肪酸的种类与结构对稠油的降粘效果影响较大,胺的种类与结构对稠油降粘效果影响小。三聚甲醛交联的多胺酰胺侧短烷基链(C16)的降粘效果最高达32.7%。
以脂肪痠和多胺為原料閤成多胺酰胺,用三聚甲醛進一步交聯多胺酰胺,將其作為稠油流動性改進劑,評價瞭其對稠油凝點和粘度的影響。結果錶明,三聚甲醛交聯的多胺酰胺型稠油流動性改進劑有一定的降凝作用,最高為2.2℃。三聚甲醛交聯的多胺酰胺型稠油流動性改進劑中脂肪痠的種類與結構對稠油的降粘效果影響較大,胺的種類與結構對稠油降粘效果影響小。三聚甲醛交聯的多胺酰胺側短烷基鏈(C16)的降粘效果最高達32.7%。
이지방산화다알위원료합성다알선알,용삼취갑철진일보교련다알선알,장기작위주유류동성개진제,평개료기대주유응점화점도적영향。결과표명,삼취갑철교련적다알선알형주유류동성개진제유일정적강응작용,최고위2.2℃。삼취갑철교련적다알선알형주유류동성개진제중지방산적충류여결구대주유적강점효과영향교대,알적충류여결구대주유강점효과영향소。삼취갑철교련적다알선알측단완기련(C16)적강점효과최고체32.7%。
Polyamine amide was prepared from fatty acid, polyamine and trioxane as raw materials. The effect of flow improvers on the pour point and viscosity of heavy oil was evaluated. The result indicated this series of a new type flow improver could depress the pour point of heavy oil, among which the highest pour point depression was 2.2℃. This series of a new type flow improver also could reduce the viscosity of heavy oil. Date analysis showed that the amine structure effect on the efifciency greatly, while fatty acid structure was insigniifcant. When polyamine amide molecular main chain contained less nitrogen atoms, efifciency of short chain alkyl structure was slightly better than the long chain alkyl. But as the number of nitrogen atoms increased, efifciency of long chain alkyl structure on heavy oil viscosity reduction increased. The most effective polyamine amide showed potent viscosity reduction and the highest reduction rate of 32.7% with less nitrogen atoms and short chains.