合成材料老化与应用
閤成材料老化與應用
합성재료노화여응용
SYNTHETIC MATERIALS AGING AND APPLICATION
2014年
1期
41-45
,共5页
等规聚丙稀%β成核剂%β晶型%结晶行为
等規聚丙稀%β成覈劑%β晶型%結晶行為
등규취병희%β성핵제%β정형%결정행위
isotactic polypropylene%βnucleating agent%βcrystal%crystallization behavior
研究了一种β成核剂( CHB-5)的含量对等规聚丙烯( iPP)结晶性能和力学性能的影响。用广角X射线衍射(WAXD)研究CHB-5诱导iPP晶型的变化,用差示扫描量热法(DSC)分析CHB-5对iPP熔融行为和结晶行为的影响,用偏光显微镜( POM)观察CHB-5诱导iPP结晶形态的变化。结果表明,CHB-5的加入使iPP的成核能力增强;CHB-5可降低iPP的熔融温度,提高其结晶温度和结晶起始温度,加快结晶速率;CHB-5能降低球晶尺寸;CHB-5的加入可使iPP缺口冲击强度提高。
研究瞭一種β成覈劑( CHB-5)的含量對等規聚丙烯( iPP)結晶性能和力學性能的影響。用廣角X射線衍射(WAXD)研究CHB-5誘導iPP晶型的變化,用差示掃描量熱法(DSC)分析CHB-5對iPP鎔融行為和結晶行為的影響,用偏光顯微鏡( POM)觀察CHB-5誘導iPP結晶形態的變化。結果錶明,CHB-5的加入使iPP的成覈能力增彊;CHB-5可降低iPP的鎔融溫度,提高其結晶溫度和結晶起始溫度,加快結晶速率;CHB-5能降低毬晶呎吋;CHB-5的加入可使iPP缺口遲擊彊度提高。
연구료일충β성핵제( CHB-5)적함량대등규취병희( iPP)결정성능화역학성능적영향。용엄각X사선연사(WAXD)연구CHB-5유도iPP정형적변화,용차시소묘량열법(DSC)분석CHB-5대iPP용융행위화결정행위적영향,용편광현미경( POM)관찰CHB-5유도iPP결정형태적변화。결과표명,CHB-5적가입사iPP적성핵능력증강;CHB-5가강저iPP적용융온도,제고기결정온도화결정기시온도,가쾌결정속솔;CHB-5능강저구정척촌;CHB-5적가입가사iPP결구충격강도제고。
The effect of a kind of βnucleating agent ( CHB-5) content on crystallization properties and mechani-cal properties of isotactic polypropylene ( iPP ) was studied.The influence of iPP induced by CHB -5 were re-searched by means of wide angle X ray diffraction ( WAXD)、differential scanning calorimetry ( DSC)、polarizing opti-cal microscope ( POM).The change of the crystal structure was studied by using the WAXD;The melting behavior and crystallization behavior was researched by using the DSC;The crystalline form was discussed by using POM.As a result ,with the addition of CHB -5,nucleated iPP showed a larger nuclear capability ,a higher crystallization tempera-ture and initial crystallization temperature ,a faster crystallization rate.The melting temperature was decreased and the spherulites of nucleated iPP became small.Meanwhile ,the impact strength of nucleated iPP appeared increase.