CAJ | 학술논문

随着我国裂解制乙烯的工业不断壮大，副产物C4烯烃的产量大幅提高，如何有效利用大量生产的C4烯烃是我国亟待解决的问题。实验组以省部级项目“C4烯烃叠合生产高碳烯烃关键技术开发”为背景，研究C4烯烃下游产品的开发利用。本课题以烯烃环氧化胺化路线合成叔胺，主要研究高碳烯烃在胺化过程中环氧化物的合成，将 C4烯烃最终转化到精细化工领域，在有效的解决我国大量 C4烯烃的同时，提高了精细化工产品的利用率。烯烃的环氧化物在有机化学中应用广泛，它即可以做一些有机合成反应的中间体，也可以作为有机原料，在有机合成，如药物、精细产品、高分子化合物的合成方面应用非常广泛。因此，烯烃环氧化胺化路线不仅可以实现烯烃到脂肪胺的转化，还可以拓宽高碳烯烃的有效利用途径。
수착아국렬해제을희적공업불단장대，부산물C4희경적산량대폭제고，여하유효이용대량생산적C4희경시아국극대해결적문제。실험조이성부급항목“C4희경첩합생산고탄희경관건기술개발”위배경，연구C4희경하유산품적개발이용。본과제이희경배양화알화로선합성숙알，주요연구고탄희경재알화과정중배양화물적합성，장 C4희경최종전화도정세화공영역，재유효적해결아국대량 C4희경적동시，제고료정세화공산품적이용솔。희경적배양화물재유궤화학중응용엄범，타즉가이주일사유궤합성반응적중간체，야가이작위유궤원료，재유궤합성，여약물、정세산품、고분자화합물적합성방면응용비상엄범。인차，희경배양화알화로선불부가이실현희경도지방알적전화，환가이탁관고탄희경적유효이용도경。
With the growing of China's ethylene cracking industry, the production of C4 olefin has substantially increased. How to effectively use the C4 olefin is a problem to be solved. Our experimental group’s job is to study the development and utilization of C4 olefins’ downstream products, based on a provincial project. The topic works on the olefins epoxidation-amination route, mainly research the synthesis of epoxidation compounds produced in the amination process. Finally the C4 olefin will be transformed into the filed of fine chemicals. This is not only a way to use C4 olefin, but also an improvement to utilization of fine chemical products. Olefin epoxides are widely used in organic chemistry; it can act as some intermediates of organic synthesis reactions, also as organic ingredients in organic synthesis, petrochemical, pharmaceutical, perfume, electronics industry, fine chemical, polymer synthesis materials and other fields. Therefore, the olefins epoxidation-amination route not only can achieve the conversion of olefin to fatty amines, but also broaden the effective way to utilize higher olefins.