华南理工大学学报(自然科学版)
華南理工大學學報(自然科學版)
화남리공대학학보(자연과학판)
JOURNAL OF SOUTH CHINA UNIVERSITY OF TECHNOLOGY(NATURAL SCIENCE EDITION)
2013年
12期
43-48
,共6页
莫立焕%周志明%王玉峰%鲁礼成
莫立煥%週誌明%王玉峰%魯禮成
막립환%주지명%왕옥봉%로례성
废水处理%烟草薄片废水%铁改性膨润土%非均相Fenton%响应面分析
廢水處理%煙草薄片廢水%鐵改性膨潤土%非均相Fenton%響應麵分析
폐수처리%연초박편폐수%철개성팽윤토%비균상Fenton%향응면분석
wastewater treatment%tobacco slice wastewater%Fe-Bent%heterogeneous Fenton%response surface analysis
以铁离子交换改性钠基膨润土,制得一种非均相Fenton催化剂,利用扫描电镜和X射线衍射仪对催化剂进行了表征,并将其用于光催化深度处理造纸法烟草薄片废水.采用响应面分析法通过建立出水CODCr与各因素之间的Box-Behnken 数学模型,对光催化处理工艺进行优化.结果表明:在最佳实验条件(pH值2.7、H2 O2用量0.2%、催化剂用量1750 mg/L)下,处理后废水CODCr低至60.44 mg/L;铁改性膨润土在反应过程中具有较低的铁溶出量和良好的重复使用性.
以鐵離子交換改性鈉基膨潤土,製得一種非均相Fenton催化劑,利用掃描電鏡和X射線衍射儀對催化劑進行瞭錶徵,併將其用于光催化深度處理造紙法煙草薄片廢水.採用響應麵分析法通過建立齣水CODCr與各因素之間的Box-Behnken 數學模型,對光催化處理工藝進行優化.結果錶明:在最佳實驗條件(pH值2.7、H2 O2用量0.2%、催化劑用量1750 mg/L)下,處理後廢水CODCr低至60.44 mg/L;鐵改性膨潤土在反應過程中具有較低的鐵溶齣量和良好的重複使用性.
이철리자교환개성납기팽윤토,제득일충비균상Fenton최화제,이용소묘전경화X사선연사의대최화제진행료표정,병장기용우광최화심도처리조지법연초박편폐수.채용향응면분석법통과건립출수CODCr여각인소지간적Box-Behnken 수학모형,대광최화처리공예진행우화.결과표명:재최가실험조건(pH치2.7、H2 O2용량0.2%、최화제용량1750 mg/L)하,처리후폐수CODCr저지60.44 mg/L;철개성팽윤토재반응과정중구유교저적철용출량화량호적중복사용성.
A heterogeneous Fenton catalyst,namely Fe-Bent,was prepared from Na-Bent through cation exchange and was characterized by means of scan electron microscopy and X-ray diffraction.Then,the catalyst was used for the advanced treatment of papermaking-reconstituted tobacco slice wastewater,and a Box-Behnken mathematical model describing the relationship between wastewater CODCr and affecting factors was then established via the re-sponse surface analysis,with the photo-catalytic treatment process being finally optimized.The results show that (1)under optimal conditions,that is,an initial pH value of2.7,a H2O2 dosage of0.2%and a catalyst dosage of 1 750 mg/L,the CODCr is as low as 60.44 mg/L;(2)only a small amount of Fe ions leach from Fe-Bent during the reaction;and (3)the prepared catalyst can be easily recovered and reused.