广州化工
廣州化工
엄주화공
GUANGZHOU CHEMICAL INDUSTRY AND TECHNOLOGY
2013年
24期
73-75
,共3页
赵玉叶%鲍远志%翁世兵%柴多里
趙玉葉%鮑遠誌%翁世兵%柴多裏
조옥협%포원지%옹세병%시다리
双层包覆红磷%阻燃等级%聚丙烯
雙層包覆紅燐%阻燃等級%聚丙烯
쌍층포복홍린%조연등급%취병희
DERP%flame retardant rating%PP
采用沉淀法制备双层包覆红磷( DERP),通过FESEM、 XPS、 TG、吸湿性测试对其进行了表征。结果表明:红磷表面形成均匀的包覆层,包覆率达到97.18%,包覆后的红磷吸湿性也得到较大改善,着火点提高到430℃。将阻燃剂DERP添加到聚丙烯中,质量分数为5%时,阻燃级别可达到UL 94 V-0级。
採用沉澱法製備雙層包覆紅燐( DERP),通過FESEM、 XPS、 TG、吸濕性測試對其進行瞭錶徵。結果錶明:紅燐錶麵形成均勻的包覆層,包覆率達到97.18%,包覆後的紅燐吸濕性也得到較大改善,著火點提高到430℃。將阻燃劑DERP添加到聚丙烯中,質量分數為5%時,阻燃級彆可達到UL 94 V-0級。
채용침정법제비쌍층포복홍린( DERP),통과FESEM、 XPS、 TG、흡습성측시대기진행료표정。결과표명:홍린표면형성균균적포복층,포복솔체도97.18%,포복후적홍린흡습성야득도교대개선,착화점제고도430℃。장조연제DERP첨가도취병희중,질량분수위5%시,조연급별가체도UL 94 V-0급。
The Double Encapsulated Red Phosphorus ( DERP ) which was prepared by deposition sedimentation method was investigated by FESEM, XPS, and TG analysis means.The result indicated that an uniform layer of encapsulation was formed, 97.18% of the red phosphorus was encapsulated, the water absorption rate was lowered apparently and the ignition point of red phosphorous was improved to 430 ℃.Adding the DERP to the polypropylene ( PP) for fire retardant, the flame retardant reached UL 94 V-0 class after adding 5%DERP.