化工学报
化工學報
화공학보
JOURNAL OF CHEMICAL INDUSY AND ENGINEERING (CHINA)
2014年
3期
1068-1075
,共8页
洪晨%邢奕%王志强%张坤%司艳晓
洪晨%邢奕%王誌彊%張坤%司豔曉
홍신%형혁%왕지강%장곤%사염효
废物处理%混凝%表面活性剂%污泥%胞外聚合物%脱水性能
廢物處理%混凝%錶麵活性劑%汙泥%胞外聚閤物%脫水性能
폐물처리%혼응%표면활성제%오니%포외취합물%탈수성능
waste treatment%coagulation%surfactant%sludge%extracellular polymeric substance%dewaterability
研究了 CaO、PAFC 联合表面活性剂预处理对污泥脱水性能的影响。以污泥滤饼含水率和比阻(SRF)作为评价污泥脱水性能的指标,通过测定污泥调理过程中胞外聚合物(EPS)含量、Zeta 电位的变化来阐明污泥脱水性能的变化。实验结果表明,十二烷基二甲基苄基氯化铵(1227)的加入导致上清液中EPS含量发生变化,有效降低了SRF和滤饼含水率,提高污泥脱水性能。CaO、PAFC和表面活性剂的联合调理污泥比单独使用表面活性剂的效果更好,CaO、PAFC 的投加不仅改善污泥脱水性能,并有助于减少表面活性剂的用量。污泥上清液中EPS及其各组分含量与污泥滤饼含水率、SRF均有较高的相关性,对污泥的脱水性能有重要贡献。实验中确定的最佳污泥调理条件是CaO投加量为66.67 mg·(g DS)-1、PAFC投加量为33.33 mg·(g DS)-1和表面活性剂投加量为56.25 mg·(g DS)-1,污泥滤饼含水率和SRF分别降至69.41%、0.294×1013 m·kg-1。
研究瞭 CaO、PAFC 聯閤錶麵活性劑預處理對汙泥脫水性能的影響。以汙泥濾餅含水率和比阻(SRF)作為評價汙泥脫水性能的指標,通過測定汙泥調理過程中胞外聚閤物(EPS)含量、Zeta 電位的變化來闡明汙泥脫水性能的變化。實驗結果錶明,十二烷基二甲基芐基氯化銨(1227)的加入導緻上清液中EPS含量髮生變化,有效降低瞭SRF和濾餅含水率,提高汙泥脫水性能。CaO、PAFC和錶麵活性劑的聯閤調理汙泥比單獨使用錶麵活性劑的效果更好,CaO、PAFC 的投加不僅改善汙泥脫水性能,併有助于減少錶麵活性劑的用量。汙泥上清液中EPS及其各組分含量與汙泥濾餅含水率、SRF均有較高的相關性,對汙泥的脫水性能有重要貢獻。實驗中確定的最佳汙泥調理條件是CaO投加量為66.67 mg·(g DS)-1、PAFC投加量為33.33 mg·(g DS)-1和錶麵活性劑投加量為56.25 mg·(g DS)-1,汙泥濾餅含水率和SRF分彆降至69.41%、0.294×1013 m·kg-1。
연구료 CaO、PAFC 연합표면활성제예처리대오니탈수성능적영향。이오니려병함수솔화비조(SRF)작위평개오니탈수성능적지표,통과측정오니조리과정중포외취합물(EPS)함량、Zeta 전위적변화래천명오니탈수성능적변화。실험결과표명,십이완기이갑기변기록화안(1227)적가입도치상청액중EPS함량발생변화,유효강저료SRF화려병함수솔,제고오니탈수성능。CaO、PAFC화표면활성제적연합조리오니비단독사용표면활성제적효과경호,CaO、PAFC 적투가불부개선오니탈수성능,병유조우감소표면활성제적용량。오니상청액중EPS급기각조분함량여오니려병함수솔、SRF균유교고적상관성,대오니적탈수성능유중요공헌。실험중학정적최가오니조리조건시CaO투가량위66.67 mg·(g DS)-1、PAFC투가량위33.33 mg·(g DS)-1화표면활성제투가량위56.25 mg·(g DS)-1,오니려병함수솔화SRF분별강지69.41%、0.294×1013 m·kg-1。
Dewatering performance of sludge modified by CaO and PAFC combined with surfactant is investigated in this study. Water content of dewatered sludge and specific resistance of filtration (SRF) are used to evaluate the sludge dewaterability, and the change of sludge dewaterability is explained by measuring variation of extracellular polymeric substance (EPS) content and Zeta potential in the conditioning process. The results show that adding surfactant can change EPS content in the filtrate, and reduce SRF and water content of dewatered sludge, and improve dewatering performance of sludge. The effect of CaO and PAFC combined with surfactant is better than individual surfactant. The addition of CaO and PAFC can both improve sludge dewaterability and contribute to reduce the addition of surfactant. The content of EPS and its components in sludge filtrate has a high correlation with the water content of dewatered sludge and SRF, and an important effect on the detwatering performance of sludge. The optimal conditions determined by experiment is that the addition amount of CaO, PAFC, surfactant is 66.67 mg·g-1, 33.33 mg·g-1, 56.25 mg·g-1, and the water content in dewatered sludge and SRF are 69.41%、0.294×1013 m·kg-1, respectively.