CAJ | 학술논문

苯胺甲醛缩合制多胺的反应是典型的第Ⅲ类反应体系，反应过程复杂。针对反应的阶段性特征，采用分段导数分析法对其进行反应器网络综合，第一阶段应采用DSR或PFR；第二阶段应采用PFR。采用不同的流程结构进行试验，结果为：采用DSR+PFR的流程结构，最终产品中二氨基二苯甲烷（MDA）含量最高；采用PFR+PFR的流程结构，最终产品中二氨基二苯甲烷(MDA)含量次之。试验结果与导数分析法分析结果一致，表明本文所用方法是有效的。
분알갑철축합제다알적반응시전형적제Ⅲ류반응체계，반응과정복잡。침대반응적계단성특정，채용분단도수분석법대기진행반응기망락종합，제일계단응채용DSR혹PFR；제이계단응채용PFR。채용불동적류정결구진행시험，결과위：채용DSR+PFR적류정결구，최종산품중이안기이분갑완（MDA）함량최고；채용PFR+PFR적류정결구，최종산품중이안기이분갑완(MDA)함량차지。시험결과여도수분석법분석결과일치，표명본문소용방법시유효적。
Synthesis of polyamine from aniline and formaldehyde is a typical type Ⅲ reaction system, so the reaction process is complex. In view of the stage characteristics of type Ⅲ reaction system, piecewise derivative analysis was used to solve the problem of its reactor network synthesis. Differential side-stream reactor(DSR) or plug flow reactor (PFR) should be used in the first reaction stage and PFR should be used in the second reaction stage. A series of experiments with different process structures were done, and the results were compared with theoretical analysis. The results of the experiments showed that the amount of methylenedianiline (MDA) was the highest with the structure of DSR and PFR. The amount of MDA was the second highest with the structure of PFR and PFR. The experimental results were consistent with the piecewise derivative analysis results, indicating the effectiveness of piecewise derivative analysis.