CAJ | 학술논문

采用脉冲电沉积结合阳极氧化铝模板技术制备了不同生长方向的闪锌矿型InSb纳米线阵列。结果表明，控制电解液中十二烷基硫酸钠(SDS)的浓度，可使纳米线的择优生长方向从[400]向[220]方向转变。利用X射线衍射仪、场发射扫描电子显微镜、高分辨透射电子显微镜对所制备纳米线的相组成和微结构进行了表征。激光拉曼光谱结果表明，不同生长方向的InSb纳米线阵列的拉曼光谱有明显差异。与体材料相比， InSb纳米线阵列的红外吸收声子散射峰发生强烈红移，其吸收带边发生了明显蓝移。
채용맥충전침적결합양겁양화려모판기술제비료불동생장방향적섬자광형InSb납미선진렬。결과표명，공제전해액중십이완기류산납(SDS)적농도，가사납미선적택우생장방향종[400]향[220]방향전변。이용X사선연사의、장발사소묘전자현미경、고분변투사전자현미경대소제비납미선적상조성화미결구진행료표정。격광랍만광보결과표명，불동생장방향적InSb납미선진렬적랍만광보유명현차이。여체재료상비， InSb납미선진렬적홍외흡수성자산사봉발생강렬홍이，기흡수대변발생료명현람이。
Zinc-blende-type InSb nanowire arrays with different growth orientations were synthesized in porous anodic alumina membrane by pulse electrodeposition. It is found that the growth orientation of InSb nanowires changes from [400] to [220] direction by controlling the concentration of sodium dodecyl sulfate(SDS) in the electrolyte. The phases and microstructure of the obtained nanowires were analyzed using powder X-ray diffraction, scanning electron microscopy and high-resolution transmission electron microscopy. The laser Raman spectra of the InSb nanowire arrays grown along different directions show distinctly different Raman features. Compared with the bulk materials, the phonon scattering peaks of the InSb nanowire arrays are severely red-shifted while its corresponding absorption band is blue-shifted.