功能材料
功能材料
공능재료
JOURNAL OF FUNCTIONAL MATERIALS
2014年
5期
5060-5064
,共5页
王景然%马保国%李相国%李海南%田振
王景然%馬保國%李相國%李海南%田振
왕경연%마보국%리상국%리해남%전진
重金属%固化%磷酸镁水泥
重金屬%固化%燐痠鎂水泥
중금속%고화%린산미수니
heavy metal%solidification%magnesium phosphate cement
利用磷酸镁水泥对Pb2+、Zn2+、Cu2+重金属硝酸盐进行固化,研究其浸出率变化规律,并对不同种类重金属对磷酸镁水泥水化产物种类、形貌及其微区元素进行了探讨.研究表明,磷酸镁水泥对重金属进行固化效果Pb2+>Cu2+>Zn2+,浸出毒性数值远低于国家标准要求.Pb2+促进了水化产物的生成,Cu2+和Zn2+抑制水化.采用 EDS 能谱分别检测水化产物中Pb、Zn和Cu,分析磷酸镁水泥对重金属硝酸盐稳定/固化效果.
利用燐痠鎂水泥對Pb2+、Zn2+、Cu2+重金屬硝痠鹽進行固化,研究其浸齣率變化規律,併對不同種類重金屬對燐痠鎂水泥水化產物種類、形貌及其微區元素進行瞭探討.研究錶明,燐痠鎂水泥對重金屬進行固化效果Pb2+>Cu2+>Zn2+,浸齣毒性數值遠低于國傢標準要求.Pb2+促進瞭水化產物的生成,Cu2+和Zn2+抑製水化.採用 EDS 能譜分彆檢測水化產物中Pb、Zn和Cu,分析燐痠鎂水泥對重金屬硝痠鹽穩定/固化效果.
이용린산미수니대Pb2+、Zn2+、Cu2+중금속초산염진행고화,연구기침출솔변화규률,병대불동충류중금속대린산미수니수화산물충류、형모급기미구원소진행료탐토.연구표명,린산미수니대중금속진행고화효과Pb2+>Cu2+>Zn2+,침출독성수치원저우국가표준요구.Pb2+촉진료수화산물적생성,Cu2+화Zn2+억제수화.채용 EDS 능보분별검측수화산물중Pb、Zn화Cu,분석린산미수니대중금속초산염은정/고화효과.
The leaching rate of magnesium phosphate cement with Pb2+,Zn2+,Cu2+ were studied.The kind, morphology and micro area elements of hydration products of magnesium phosphate cement added heavy met-als,were discussed in this paper.Research shows that:the magnesium phosphate cement on heavy metal solidi-fication effect of Pb2+>Cu2+> Zn2+,while the value of leaching toxicity was far lower than the national stand-ard requirements.Pb2+ could promote the formation of hydration products,while Cu2+ and Zn2+ were opposite. Pb,Cu and Zn were respectively detected used the EDS spectrum detection,which was proved that it cans or not stabilization/solidification of heavy metals in the hydration products of magnesium phosphate cement.