南京林业大学学报(自然科学版)
南京林業大學學報(自然科學版)
남경임업대학학보(자연과학판)
JOURNAL OF NANJING FORESTRY UNIVERSITY(NATURAL SCIENCE EDITION)
2014年
2期
161-164
,共4页
燕乐乐%刘幸平%程康华%李靖
燕樂樂%劉倖平%程康華%李靖
연악악%류행평%정강화%리정
三唑类化合物%抑菌效果%木材防腐剂
三唑類化閤物%抑菌效果%木材防腐劑
삼서류화합물%억균효과%목재방부제
triazole%antibacterial effect%wood preservatives
为了获得高活性的木材防腐剂,以1,3-二氯苯为原料,依次经过傅克酰基化、烷基化、环氧化及开环反应得到6种三唑类化合物Y-4( a-f),且所有化合物的结构经过MS和1 H-NMR确定;采用滤纸片法对常见的两种霉菌和两种木腐菌进行活性抑菌实验。结果表明:6种化合物中,Y-4d表现出的抗菌谱较广,对木材霉菌和腐朽菌都有抑制作用,但对腐朽菌的抑制效果不如Y-4c和Y-4f,Y-4c和Y-4f对木材腐朽菌表现出较强的抑制能力。
為瞭穫得高活性的木材防腐劑,以1,3-二氯苯為原料,依次經過傅剋酰基化、烷基化、環氧化及開環反應得到6種三唑類化閤物Y-4( a-f),且所有化閤物的結構經過MS和1 H-NMR確定;採用濾紙片法對常見的兩種黴菌和兩種木腐菌進行活性抑菌實驗。結果錶明:6種化閤物中,Y-4d錶現齣的抗菌譜較廣,對木材黴菌和腐朽菌都有抑製作用,但對腐朽菌的抑製效果不如Y-4c和Y-4f,Y-4c和Y-4f對木材腐朽菌錶現齣較彊的抑製能力。
위료획득고활성적목재방부제,이1,3-이록분위원료,의차경과부극선기화、완기화、배양화급개배반응득도6충삼서류화합물Y-4( a-f),차소유화합물적결구경과MS화1 H-NMR학정;채용려지편법대상견적량충매균화량충목부균진행활성억균실험。결과표명:6충화합물중,Y-4d표현출적항균보교엄,대목재매균화부후균도유억제작용,단대부후균적억제효과불여Y-4c화Y-4f,Y-4c화Y-4f대목재부후균표현출교강적억제능력。
In order to get a wood preservative with higher efficiency, six compounds Y-4( a-f) were synthesized using 1, 3-dichlorobenzene as the starting material by Friedel-crafts acetylation, alkylation, epoxidation, and ring-opening re-action. The structures of these compounds were determined by MS and 1 H-NMR. Antifungal activities of these compounds were evaluated by two moulds and two decay fungi with Filter paper diffusion. The results indicated that Y-4d had a broad spectrum of antibacteria on moulds and decay fungi, but Y-4c and Y-4f had better antibacterial effect on decay fungi.