CAJ | 학술논문

在H2 O2/醋酸氧化柴油体系中，采用季铵盐型表面活性剂和季铵盐型Gemini表面活性剂作为相转移催化剂（PTC），进行柴油的催化氧化脱硫研究。比较了不同碳链长度的季铵盐型表面活性剂和季铵盐型Gemini表面活性剂的脱硫效果，考察了双子表面活性剂[C12 H25-N＋-（C H2）2-N＋-C12 H25]·2Br -（C12-2-C12·2Br -）用量、氧化剂用量、反应温度以及反应时间对脱硫效果的影响。结果表明，以C12-2-C12·2Br -作为相转移催化剂，m（PTC）∶ m（柴油）＝0．0025，V （氧化体系）∶V（柴油）＝0．2，反应温度为70℃，反应时间为1．5 h 时，柴油脱硫率最高可达84．76％，柴油收率为94．52％。
재H2 O2/작산양화시유체계중，채용계안염형표면활성제화계안염형Gemini표면활성제작위상전이최화제（PTC），진행시유적최화양화탈류연구。비교료불동탄련장도적계안염형표면활성제화계안염형Gemini표면활성제적탈류효과，고찰료쌍자표면활성제[C12 H25-N＋-（C H2）2-N＋-C12 H25]·2Br -（C12-2-C12·2Br -）용량、양화제용량、반응온도이급반응시간대탈류효과적영향。결과표명，이C12-2-C12·2Br -작위상전이최화제，m（PTC）∶ m（시유）＝0．0025，V （양화체계）∶V（시유）＝0．2，반응온도위70℃，반응시간위1．5 h 시，시유탈류솔최고가체84．76％，시유수솔위94．52％。
Catalytic oxidation desulfurization of diesel in the H2O2/acetate oxidative diesel des-ulfurization system by quaternary ammonium surfactants and quaternary ammonium Gemini sur-factants as phase transfer catalyst (PTC) was studied .The desulfurization effect of quaternary ammonium surfactants and quaternary ammonium Gemini surfactants with different carbon chain was compared .Furthermore ,the effects of [C12H25-N+-(CH2)2-N+-C12H25]· 2Br-dosage ,oxi-dant dosage ,reaction temperature and reaction time on the desulfurization performance were in-vestigated .The result showed that the desulfurization rate of diesel fuel could be up to 84 .76%and the diesel yield reached 94 .52% while the mass ratio of PTC and diesel fuel was 0.002 5 and volume ratio of oxidation system and diesel fuel was 0.2 after 1.5h in reaction at 70 ℃ ,taking [C12H25-N+-(CH2)2-N+-C12H25] · 2Br-as the phase transfer catalyst .