石油炼制与化工
石油煉製與化工
석유련제여화공
PETROLEUM PROCESSING AND PETROCHEMICALS
2014年
3期
25-29
,共5页
黄新龙%王洪彬%张瑞风%李和杰
黃新龍%王洪彬%張瑞風%李和傑
황신룡%왕홍빈%장서풍%리화걸
焦化%浅度热裂化%减黏%加热炉%液体收率
焦化%淺度熱裂化%減黏%加熱爐%液體收率
초화%천도열열화%감점%가열로%액체수솔
coking%mild thermal cracking%visbreaking%furnace%liquid yield
为了提高延迟焦化的液体产品收率,中国石化洛阳工程有限公司对现有工艺进行改进,把浅度热裂化反应和深度热裂化反应有机地结合在一起,开发出了ADCP新工艺。在新研制的减黏-焦化-连续蒸馏联合试验装置上考察了劣质重油浅度热裂化深度对焦化产品分布的影响。结果表明,当重油的减黏率分别为33.03%,52.43%,78.21%时,与常规工艺相比,液体产品收率分别提高了0.48,0.97,1.71百分点,其中轻质油收率分别提高了1.04,1.11,2.19百分点,轻质油收率的提高主要体现在柴油馏分收率提高上,而焦化汽油、柴油和蜡油等产品的性质与常规工艺的产品无明显区别,不会影响各产品的后续加工过程。
為瞭提高延遲焦化的液體產品收率,中國石化洛暘工程有限公司對現有工藝進行改進,把淺度熱裂化反應和深度熱裂化反應有機地結閤在一起,開髮齣瞭ADCP新工藝。在新研製的減黏-焦化-連續蒸餾聯閤試驗裝置上攷察瞭劣質重油淺度熱裂化深度對焦化產品分佈的影響。結果錶明,噹重油的減黏率分彆為33.03%,52.43%,78.21%時,與常規工藝相比,液體產品收率分彆提高瞭0.48,0.97,1.71百分點,其中輕質油收率分彆提高瞭1.04,1.11,2.19百分點,輕質油收率的提高主要體現在柴油餾分收率提高上,而焦化汽油、柴油和蠟油等產品的性質與常規工藝的產品無明顯區彆,不會影響各產品的後續加工過程。
위료제고연지초화적액체산품수솔,중국석화락양공정유한공사대현유공예진행개진,파천도열열화반응화심도열열화반응유궤지결합재일기,개발출료ADCP신공예。재신연제적감점-초화-련속증류연합시험장치상고찰료렬질중유천도열열화심도대초화산품분포적영향。결과표명,당중유적감점솔분별위33.03%,52.43%,78.21%시,여상규공예상비,액체산품수솔분별제고료0.48,0.97,1.71백분점,기중경질유수솔분별제고료1.04,1.11,2.19백분점,경질유수솔적제고주요체현재시유류분수솔제고상,이초화기유、시유화사유등산품적성질여상규공예적산품무명현구별,불회영향각산품적후속가공과정。
As the feedstocks of delayed coker become heavier and inferior,there are more challenges for coker unit,such as higher liquid product yield,long-term and safe operation,environmental protec-tion and capacity of the unit. A new process named ADCP which integrates a mild thermal cracking stage with a deep thermal cracking stage with one furnace in a coking unit is realized by LPEC for higher liquid product yield. Studies were conducted in LPEC pilot plant with visbreaking,delayed coking and continuous distillation to investigate the effect of heavy oil mild thermal cracking depth on the properties and compositions of coking products. The results show that the yields of liquid products are improved by 0. 48,0. 97 and 1. 71 percentage points,respectively when visbreaking ratios of heavy oil are 33. 03%,52. 43%and 78. 21%. The yields of light liquid products are increased by 1. 04,1. 11 and 2. 19 percentage points,respectively,compared with that of the traditional process. The improvement in light oil yields is mainly manifested in yield increase of the diesel fraction. However,the properties of ADCP products are almost the same as the ones of traditional process products,so the new process has no neg-ative effects on down-stream processes.