CAJ | 학술논문

针对中国石化荆门分公司现有两套催化裂化装置（一催和二催）的目的产品不同（一催多产低碳烯烃，二催保持较高的液体收率和汽油产率），希望通过调整工艺参数满足要求。通过实验考察了反应时间、剂油比和再生温度对产物分布和选择性的影响。结果表明：延长反应时间，热裂化反应深度会显著增加，干气选择性和氢气产率明显增加，热裂化指数明显上升；增加剂油比是保持丙烯收率、增加总液体收率的优选方案；较高的初始油剂接触温度有利于低碳烯烃的生成，但如果以汽油、柴油为目的产物，则应该适当降低再生温度和油剂的初始接触温度，而不是降低反应温度。
침대중국석화형문분공사현유량투최화열화장치（일최화이최）적목적산품불동（일최다산저탄희경，이최보지교고적액체수솔화기유산솔），희망통과조정공예삼수만족요구。통과실험고찰료반응시간、제유비화재생온도대산물분포화선택성적영향。결과표명：연장반응시간，열열화반응심도회현저증가，간기선택성화경기산솔명현증가，열열화지수명현상승；증가제유비시보지병희수솔、증가총액체수솔적우선방안；교고적초시유제접촉온도유리우저탄희경적생성，단여과이기유、시유위목적산물，칙응해괄당강저재생온도화유제적초시접촉온도，이불시강저반응온도。
Low carbon olefins and distillates are produced separately by two FCC units in Jingmen Petrochemical Company. In order to obtain high selectivity for low carbon olefins and liquid product of distillates at the same time respectively by the two units,the operation parameters were examined,in-cluding reaction time,ratio of catalyst to oil,and regeneration temperature. The results show that these parameters have different effect on the selectivity and distillates yield. As the reaction time prolonged, thermal cracking will increase,resulting in more dry gas and H2. Increasing the ratio of catalyst to oil is the better way to keep the propylene yield and increase the total liquid yield. The higher initial oil-cata-lyst contact temperature is good for low carbon olefins formation. In case of high yields of gasoline and diesel needed,the regeneration temperature must be optimized.