CAJ | 학술논문

合成了双头基多氟烷基两亲杯[4]芳烃化合物1和2，利用表面压一面积（π-A）等温线、压缩/扩张循环等温线与膜稳曲线研究了他们在空气/水相界面的成膜性能，并用紫外光谱和原子力显微镜对组装的LB膜进行了结构表征。结果表明：化合物1和2在空气/水相表面均能很好的形成稳定的Langmuir膜，取代基碳原子数的增加使得化合物2的Langmuir膜单分子面积增加，崩溃压相应减少，组装的LB膜均为H-聚集体，结构均匀，稳定性好。
합성료쌍두기다불완기량친배[4]방경화합물1화2，이용표면압일면적（π-A）등온선、압축/확장순배등온선여막은곡선연구료타문재공기/수상계면적성막성능，병용자외광보화원자력현미경대조장적LB막진행료결구표정。결과표명：화합물1화2재공기/수상표면균능흔호적형성은정적Langmuir막，취대기탄원자수적증가사득화합물2적Langmuir막단분자면적증가，붕궤압상응감소，조장적LB막균위H-취집체，결구균균，은정성호。
Amphiphilic Calix[4]arene Derivatives 1 and 2 Containing Polyfluoroalkanyl Groups were synthesized .Its Lang-muir-Blodgett (LB) film on air/water surface were characterized by π-A isotherms, the compress and outspread isotherms , the film stabilize isotherms, UV-Vis and FT-IR spectrum, atomic force microscope (AFM).The results indicate that com-pounds 1 and 2 could form stable monolayer or multilayer film with H -aggregate on air/water surface.The average molecular areas of 2 is bigger and the collapse surface pressure is smaller than 1, because of the length of substituted group .