CAJ | 학술논문

通过在阳离子结构中引入铀酰离子萃取剂磷酸三丁酯（TBP）的功能结构，设计合成了两种咪唑型离子液体，使该离子液体在硝酸介质中萃取铀酰离子时，既是稀释剂又具有萃取剂功能。利用傅里叶红外光谱（FTIR）、核磁共振（1 H NMR）和元素分析，对合成的离子液体结构进行了确认，并对硝酸介质中萃取铀酰离子进行了初步研究。结果表明：室温条件下，所合成的具有特定功能的离子液体可在硝酸介质中萃取铀酰离子，萃取率可达90％以上。
통과재양리자결구중인입유선리자췌취제린산삼정지（TBP）적공능결구，설계합성료량충미서형리자액체，사해리자액체재초산개질중췌취유선리자시，기시희석제우구유췌취제공능。이용부리협홍외광보（FTIR）、핵자공진（1 H NMR）화원소분석，대합성적리자액체결구진행료학인，병대초산개질중췌취유선리자진행료초보연구。결과표명：실온조건하，소합성적구유특정공능적리자액체가재초산개질중췌취유선리자，췌취솔가체90％이상。
Two imidazole-type task-specific ionic liquids (TSILs) were designed and synthesized through the introduction of tributyl phosphates (TBP) functional structure in cationic of the TSILs .They also can be as solvent and extractive agent for extracting uranyl ion in nitric acid media . Their structures were confirmed by using Fourier transform infrared spectrometer ( FTIR ) , nuclear magnetic resonance spectrum (1 H NMR) and element analysis . The extractive performances of these TSILs for uranyl ion in nitric acid medium were studied . Results show that these TSILs synthesized above can be used to extract uranyl ion in nitric acid media under room temperature ,and the extraction rate can reach more than 90% .