化学研究与应用
化學研究與應用
화학연구여응용
CHEMICAL RESEARCH AND APPLICATION
2014年
3期
364-369
,共6页
李有桂%张元元%李春东%何刚
李有桂%張元元%李春東%何剛
리유계%장원원%리춘동%하강
四硫富瓦烯%离子液体%电化学性质%阳离子识别
四硫富瓦烯%離子液體%電化學性質%暘離子識彆
사류부와희%리자액체%전화학성질%양리자식별
tetrathiafulvalene%ionic liquid%electrochemical property%cationic identification
在甲醇钠的作用下,2分子的2,3-二(2′-氰乙基硫基)-6,7-二丁硫基四硫富瓦与2分子的2,6-二(氯甲基)吡啶反应生成四硫富瓦烯-吡啶结构单元的新型环蕃(3)。在离子液中测定了新型环蕃3的电化学性质,并研究了其对金属离子识别的性能。实验结果表明:在离子液中,环蕃中四硫富瓦烯单元更加容易被氧化或还原,而且其紫外吸收也显著增强;同时发现Pb2+对这种新型环蕃化合物的紫外吸收和氧化还原电位的影响最为明显,其对Pb2+有一定的选择性识别功能,Cu2+能够破坏TTF结构单元。
在甲醇鈉的作用下,2分子的2,3-二(2′-氰乙基硫基)-6,7-二丁硫基四硫富瓦與2分子的2,6-二(氯甲基)吡啶反應生成四硫富瓦烯-吡啶結構單元的新型環蕃(3)。在離子液中測定瞭新型環蕃3的電化學性質,併研究瞭其對金屬離子識彆的性能。實驗結果錶明:在離子液中,環蕃中四硫富瓦烯單元更加容易被氧化或還原,而且其紫外吸收也顯著增彊;同時髮現Pb2+對這種新型環蕃化閤物的紫外吸收和氧化還原電位的影響最為明顯,其對Pb2+有一定的選擇性識彆功能,Cu2+能夠破壞TTF結構單元。
재갑순납적작용하,2분자적2,3-이(2′-청을기류기)-6,7-이정류기사류부와여2분자적2,6-이(록갑기)필정반응생성사류부와희-필정결구단원적신형배번(3)。재리자액중측정료신형배번3적전화학성질,병연구료기대금속리자식별적성능。실험결과표명:재리자액중,배번중사류부와희단원경가용역피양화혹환원,이차기자외흡수야현저증강;동시발현Pb2+대저충신형배번화합물적자외흡수화양화환원전위적영향최위명현,기대Pb2+유일정적선택성식별공능,Cu2+능구파배TTF결구단원。
With the effect of sodium methoxide,two molecular of 2,3-bis(2′-cyanoethylthio)-6,7-bis(buthylthio)-tetrathiafulvalene reacted with two molecular of 2,6-bis( chloromomethyl) pyridine to afford a novel tetrathiafulvalene-pyridine structure unit-cyclo-phane(3). Electrochemical properties of cyclophane 3 were determined and its recognition for metal ions were also investigated. The experiment results showed that tetrathiafulvalene units of the novel cyclophane were more easily to be oxidized or reduced in ionic liquid. The UV-vis absorption spectrum and redox property of the TTF cyclophane showed remarkable sensing and coordinating properties to Pb2+,so the TTF cyclophane could selectively recognize Pb2+ by the unique properties. The tetrathiafulvalene structure units was destroyed by Cu2+.