伊犁师范学院学报(自然科学版)
伊犛師範學院學報(自然科學版)
이리사범학원학보(자연과학판)
JOURNAL OF ILI NORMAL UNIVERSITY
2014年
1期
30-33
,共4页
肖宇%周恒为%丁捷%徐凡华%衡晓%雷婷%尹红梅
肖宇%週恆為%丁捷%徐凡華%衡曉%雷婷%尹紅梅
초우%주항위%정첩%서범화%형효%뢰정%윤홍매
钛酸锶钡%介电常数%介电损耗%玻璃化转变
鈦痠鍶鋇%介電常數%介電損耗%玻璃化轉變
태산송패%개전상수%개전손모%파리화전변
BST%permittivity%dielectric loss%glass transition
采用固相反应方法制备出(1-x)Ba 0.2Sr0.8Ti0.98Zn0.04O3+xY2O3(x=0,0.02,0.025,0.03)陶瓷材料,并研究Y2O3掺杂对BST-Zn陶瓷样品结构和介电性能的影响,得到以下结论:(1)一定量的Y2O3掺杂,可使BST-Zn陶瓷的晶胞体积增大,晶粒尺寸减小;(2)频率为10Hz时,当掺入2%Y 2 O 3时,ε'最大值可达到885,此时介电损耗为0.024;(3)Y 2 O 3掺入使得低温的弥散相变转化向极化玻璃化转变,并在250K和350K附近出现新的弛豫过程.
採用固相反應方法製備齣(1-x)Ba 0.2Sr0.8Ti0.98Zn0.04O3+xY2O3(x=0,0.02,0.025,0.03)陶瓷材料,併研究Y2O3摻雜對BST-Zn陶瓷樣品結構和介電性能的影響,得到以下結論:(1)一定量的Y2O3摻雜,可使BST-Zn陶瓷的晶胞體積增大,晶粒呎吋減小;(2)頻率為10Hz時,噹摻入2%Y 2 O 3時,ε'最大值可達到885,此時介電損耗為0.024;(3)Y 2 O 3摻入使得低溫的瀰散相變轉化嚮極化玻璃化轉變,併在250K和350K附近齣現新的弛豫過程.
채용고상반응방법제비출(1-x)Ba 0.2Sr0.8Ti0.98Zn0.04O3+xY2O3(x=0,0.02,0.025,0.03)도자재료,병연구Y2O3참잡대BST-Zn도자양품결구화개전성능적영향,득도이하결론:(1)일정량적Y2O3참잡,가사BST-Zn도자적정포체적증대,정립척촌감소;(2)빈솔위10Hz시,당참입2%Y 2 O 3시,ε'최대치가체도885,차시개전손모위0.024;(3)Y 2 O 3참입사득저온적미산상변전화향겁화파리화전변,병재250K화350K부근출현신적이예과정.
In this paper, (1-x)Ba 0.2 Sr 0.8 Ti 0.98 Zn 0.04 O 3+xY 2 O 3(x=0,0.02,0.025,0.03)ceramic samples which based on 4at% ZnO-doped Ba0.2Sr0.8TiO3 (BST-Zn) ceramics were prepared by the conventional solid-state reaction technique. The effect of Y2O3-doped on microstructures and dielectric properties of the BST-Zn simples were studied systematically. The results show that: (1) With doping suitable amount of Y2O3 maximum contents, the simples’ cell volume increases and grain size decreases;(2) It is found that the dielectric constant is 885 and the dielectric loss is 0.024, when doped 2% Y2O3 in BST-Zn ceramic at 10Hz frequency; (3) with the the Y2O3 doping, BST-Zn’s dispersion phase transition turn into the polarization glass transition phase transition in low temperature area, and two relaxation processes have been found at the area of 250K and 350K.