化工学报
化工學報
화공학보
JOURNAL OF CHEMICAL INDUSY AND ENGINEERING (CHINA)
2014年
10期
4063-4070
,共8页
谭丕强%杜加振%胡志远%楼狄明
譚丕彊%杜加振%鬍誌遠%樓狄明
담비강%두가진%호지원%루적명
SCR%柴油机%污染%模型%尿素分解效率%NOx转化率%运行参数
SCR%柴油機%汙染%模型%尿素分解效率%NOx轉化率%運行參數
SCR%시유궤%오염%모형%뇨소분해효솔%NOx전화솔%운행삼수
SCR%diesel engine%pollution%model%urea decomposition efficiency%NOx conversion efficiency%operating parameter
建立了柴油机选择性催化还原SCR系统的仿真模型,提出了尿素分解效率的概念。研究了排气温度、NH3存储量、NO2/NOx、NH3/NOx等关键运行参数对NOx转化率的影响。研究结果表明,随着排气流速的减小和排气温度的增加,尿素分解效率总体呈升高趋势。进行了不同温度下NOx转化率的评价试验研究,仿真结果和试验结果吻合良好。随NH3存储量的增加,NOx转化率呈上升趋势。随排气温度的升高,NOx转化率持续上升,当温度超过某一值后趋于稳定。随NO2/NOx的增加,NOx转化率逐渐上升,当NO2/NOx超过50%后,NOx转化率则有所下降;NOx转化率随NH3/NOx的增大而上升,当排气温度较高时,其影响较为明显。
建立瞭柴油機選擇性催化還原SCR繫統的倣真模型,提齣瞭尿素分解效率的概唸。研究瞭排氣溫度、NH3存儲量、NO2/NOx、NH3/NOx等關鍵運行參數對NOx轉化率的影響。研究結果錶明,隨著排氣流速的減小和排氣溫度的增加,尿素分解效率總體呈升高趨勢。進行瞭不同溫度下NOx轉化率的評價試驗研究,倣真結果和試驗結果吻閤良好。隨NH3存儲量的增加,NOx轉化率呈上升趨勢。隨排氣溫度的升高,NOx轉化率持續上升,噹溫度超過某一值後趨于穩定。隨NO2/NOx的增加,NOx轉化率逐漸上升,噹NO2/NOx超過50%後,NOx轉化率則有所下降;NOx轉化率隨NH3/NOx的增大而上升,噹排氣溫度較高時,其影響較為明顯。
건립료시유궤선택성최화환원SCR계통적방진모형,제출료뇨소분해효솔적개념。연구료배기온도、NH3존저량、NO2/NOx、NH3/NOx등관건운행삼수대NOx전화솔적영향。연구결과표명,수착배기류속적감소화배기온도적증가,뇨소분해효솔총체정승고추세。진행료불동온도하NOx전화솔적평개시험연구,방진결과화시험결과문합량호。수NH3존저량적증가,NOx전화솔정상승추세。수배기온도적승고,NOx전화솔지속상승,당온도초과모일치후추우은정。수NO2/NOx적증가,NOx전화솔축점상승,당NO2/NOx초과50%후,NOx전화솔칙유소하강;NOx전화솔수NH3/NOx적증대이상승,당배기온도교고시,기영향교위명현。
A simulation model for selective catalytic reduction (SCR) of exhaust gas from diesel engine is established, and a concept of urea decomposition efficiency is proposed. Effects of exhaust gas temperature, NH3 storage, NO2/NOx ratio and NH3/NOx ratio on the NOx conversion efficiency are studied. The results show that the urea decomposition efficiency increases with decreasing exhaust gas flow rate and rising exhaust gas temperature. Special evaluating experiments for NOx conversion efficiency under various temperatures were performed. The data obtained by simulation show good agreement with the experimental results. The results show that the NOx conversion efficiency increases with the NH3 storage capacity rising. Similarly, the NOx conversion efficiency increases with rising exhaust gas temperature, and it gets stable when the exhaust gas temperature reaches a certain value. Increasing NO2/NOx ratio can also improve the NOx conversion efficiency, but the opposite phenomenon occurs when the NO2/NOx ratio is greater than 50%. With increase of NH3/NOx ratio, the NOx conversion efficiency ascends, and the influence is obvious when the exhaust gas temperature is high.