化工学报
化工學報
화공학보
JOURNAL OF CHEMICAL INDUSY AND ENGINEERING (CHINA)
2014年
10期
4025-4031
,共7页
袁迎%刘会娥%徐明明%丁传芹%陈爽%齐选良
袁迎%劉會娥%徐明明%丁傳芹%陳爽%齊選良
원영%류회아%서명명%정전근%진상%제선량
微乳液%相变%最佳盐度%混合无机盐%效率参数%预测
微乳液%相變%最佳鹽度%混閤無機鹽%效率參數%預測
미유액%상변%최가염도%혼합무궤염%효솔삼수%예측
microemulsion%phase behavior%optimum salinities%salt mixtures%efficiency parameter%prediction
通过改变无机盐的种类,研究无机盐及其混合盐对十二烷基苯磺酸钠(SDBS)/正丁醇/正辛烷/水微乳液体系的影响。微乳体系随着各种盐类浓度的增加,均发生 WinsorⅠ Winsor Ⅲ Winsor Ⅱ的相变,但对不同的无机盐其最佳盐度不同。通过对6组混合无机盐体系的研究,表明混合无机盐的效率参数与混合盐组成之间存在线性关系,可以用单一无机盐的效率参数预测出混合盐的情况。以效率参数为桥梁推导出了单一无机盐与混合无机盐之间最佳盐度的关系式,可用于预测混合盐效应,发现预测结果与实验结果吻合良好。
通過改變無機鹽的種類,研究無機鹽及其混閤鹽對十二烷基苯磺痠鈉(SDBS)/正丁醇/正辛烷/水微乳液體繫的影響。微乳體繫隨著各種鹽類濃度的增加,均髮生 WinsorⅠ Winsor Ⅲ Winsor Ⅱ的相變,但對不同的無機鹽其最佳鹽度不同。通過對6組混閤無機鹽體繫的研究,錶明混閤無機鹽的效率參數與混閤鹽組成之間存在線性關繫,可以用單一無機鹽的效率參數預測齣混閤鹽的情況。以效率參數為橋樑推導齣瞭單一無機鹽與混閤無機鹽之間最佳鹽度的關繫式,可用于預測混閤鹽效應,髮現預測結果與實驗結果吻閤良好。
통과개변무궤염적충류,연구무궤염급기혼합염대십이완기분광산납(SDBS)/정정순/정신완/수미유액체계적영향。미유체계수착각충염류농도적증가,균발생 WinsorⅠ Winsor Ⅲ Winsor Ⅱ적상변,단대불동적무궤염기최가염도불동。통과대6조혼합무궤염체계적연구,표명혼합무궤염적효솔삼수여혼합염조성지간존재선성관계,가이용단일무궤염적효솔삼수예측출혼합염적정황。이효솔삼수위교량추도출료단일무궤염여혼합무궤염지간최가염도적관계식,가용우예측혼합염효응,발현예측결과여실험결과문합량호。
The influence of inorganic salts on sodium dodecyl benzene sulfonate (SDBS)/butanol/octane/water microemulsion system was investigated by changing the type of salts. Increasing cationic charge concentration of various salts in an anionic surfactant microemulsion system promoted changes in the microemulsion phase behavior from lower phase (WinsorⅠ) microemulsion through middle phase (WinsorⅢ) toward upper phase (WinsorⅡ) microemulsion. While for different inorganic salts, optimum salinities were different. Six groups of salt mixture systems were investigated. There was a linear relationship between efficiency parameter of salt mixtures and their composition, in other words, the influence of salt mixtures could be predicted by studying efficiency parameter of single inorganic salts. By using efficiency parameter as the medium, the relationship between optimum salinity of single salts and their mixtures was deduced, and could be used to predict the influence of salt mixtures. The prediction results coincided well with the experimental results.