催化学报
催化學報
최화학보
CHINESE JOURNAL OF CATALYSIS
2014年
10期
1752-1760
,共9页
罗正维%江晖%胡龙志%李丹%耿文华%韦萍
囉正維%江暉%鬍龍誌%李丹%耿文華%韋萍
라정유%강휘%호룡지%리단%경문화%위평
二氧化钛%等离子体%改性%氮掺杂%汞
二氧化鈦%等離子體%改性%氮摻雜%汞
이양화태%등리자체%개성%담참잡%홍
Titanium dioxide%Plasma%Modification%Nitrogen doping%Mercury
研究了N2/Ar介质阻挡放电处理对负载CuO的TiO2可见光光催化活性的影响.采用X射线衍射、紫外-可见分光吸收光谱、透射电镜、X射线光电子能谱和电子自旋共振进行了表征,详细考察了等离子改性参数包括气氛组成、处理时间和处理功率对改性效果的影响,并通过降解甲基橙溶液考察了可见光光催化活性.结果表明,最佳等离子处理条件为N2与Ar比例为8:2,处理时间为20 min,放电电流为1.0 A.最后,使用改性后的光催化剂对模拟含汞废水进行了处理.
研究瞭N2/Ar介質阻擋放電處理對負載CuO的TiO2可見光光催化活性的影響.採用X射線衍射、紫外-可見分光吸收光譜、透射電鏡、X射線光電子能譜和電子自鏇共振進行瞭錶徵,詳細攷察瞭等離子改性參數包括氣氛組成、處理時間和處理功率對改性效果的影響,併通過降解甲基橙溶液攷察瞭可見光光催化活性.結果錶明,最佳等離子處理條件為N2與Ar比例為8:2,處理時間為20 min,放電電流為1.0 A.最後,使用改性後的光催化劑對模擬含汞廢水進行瞭處理.
연구료N2/Ar개질조당방전처리대부재CuO적TiO2가견광광최화활성적영향.채용X사선연사、자외-가견분광흡수광보、투사전경、X사선광전자능보화전자자선공진진행료표정,상세고찰료등리자개성삼수포괄기분조성、처리시간화처리공솔대개성효과적영향,병통과강해갑기등용액고찰료가견광광최화활성.결과표명,최가등리자처리조건위N2여Ar비례위8:2,처리시간위20 min,방전전류위1.0 A.최후,사용개성후적광최화제대모의함홍폐수진행료처리.
The effect of N2/Ar dielectric barrier discharge plasma on the photocatalytic activity of CuO/TiO2 under visible light irradiation was studied. The photocatalysts were characterized by X-ray diffrac-tion, ultraviolet-visible spectrophotometry, transmission electron microscopy, X-ray photoelectron spectroscopy, and electron paramagnetic resonance spectroscopy. The plasma parameters includ-ing gas composition, treatment time, and plasma power were investigated. The activities of the plasma-treated photocatalysts were evaluated by the photodegradation of methyl orange under visible light illumination. The optimal operation conditions were N2:Ar=8:2, treatment time of 20 min, and a discharge current of 1.0 A. Simulated mercury-containing wastewater was treated by the photocatalysts.