武汉科技大学学报(自然科学版)
武漢科技大學學報(自然科學版)
무한과기대학학보(자연과학판)
JOURNAL OF WUHAN UNIVERSITY OF SCIENCE AND TECHNOLOGY(NATURAL SCIENCE EDITION)
2014年
2期
135-139
,共5页
丁曼%赵云鹏%窦有权%魏贤勇
丁曼%趙雲鵬%竇有權%魏賢勇
정만%조운붕%두유권%위현용
褐煤%CS2萃取物%甲醇萃取物%GC/MS%生物标示物
褐煤%CS2萃取物%甲醇萃取物%GC/MS%生物標示物
갈매%CS2췌취물%갑순췌취물%GC/MS%생물표시물
lignite%CS2 extract%methanol extract%GC/MS%biomarker
分别以CS2和甲醇为溶剂,辅以超声波对先锋褐煤进行常温萃取,利用傅里叶变换红外光谱(FTIR)和气相色谱/质谱(GC/M S )分析萃取物的组成及结构。结果表明,两种萃取物中共检测到124种有机化合物;CS2萃取物中烃类化合物相对含量较高,占CS2萃取物总量的52.08%,从C14~C30(除C23外)烷连续分布;甲醇萃取物中含氧和含氮化合物相对含量较高,分别占甲醇萃取物总量的39.28%和20.95%;此外还检测到多种生物标示物。
分彆以CS2和甲醇為溶劑,輔以超聲波對先鋒褐煤進行常溫萃取,利用傅裏葉變換紅外光譜(FTIR)和氣相色譜/質譜(GC/M S )分析萃取物的組成及結構。結果錶明,兩種萃取物中共檢測到124種有機化閤物;CS2萃取物中烴類化閤物相對含量較高,佔CS2萃取物總量的52.08%,從C14~C30(除C23外)烷連續分佈;甲醇萃取物中含氧和含氮化閤物相對含量較高,分彆佔甲醇萃取物總量的39.28%和20.95%;此外還檢測到多種生物標示物。
분별이CS2화갑순위용제,보이초성파대선봉갈매진행상온췌취,이용부리협변환홍외광보(FTIR)화기상색보/질보(GC/M S )분석췌취물적조성급결구。결과표명,량충췌취물중공검측도124충유궤화합물;CS2췌취물중경류화합물상대함량교고,점CS2췌취물총량적52.08%,종C14~C30(제C23외)완련속분포;갑순췌취물중함양화함담화합물상대함량교고,분별점갑순췌취물총량적39.28%화20.95%;차외환검측도다충생물표시물。
Xiangfeng lignite was extracted thoroughly with CS2 and methanol under the ultrasonic-as-sistant condition at room temperature ,and the compositions and structural characteristics of the ex-tracts were analyzed by FTIR and GC/MS .The results show that altogether 124 compounds are found in the extracts ,and in CS2 extracts the relative content of hydrocarbon compounds (HCCs) reaches 52 .08% ,which are distributed continuously from C14 to C30 expect for C23 ,while in methanol extracts the relative content of oxygen-containing compounds and nitrogen-containing compounds are compara-tively high ,accounting for 39 .28% and 20 .95% ,respectively .Additionally ,many biomarkers are detected in the extracts .