CAJ | 학술논문

以电熔镁砂、天然鳞片石墨、煤沥青、Al粉及Si粉为主要原料，以热固性酚醛树脂为结合剂，混匀后压制成M g O-C材料试样。将试样在氮气气氛下分别经1000℃×3 h、1200℃×3 h、1400℃×3 h热处理，研究热处理温度对材料物相组成、显微结构及力学性能的影响。结果表明，1000℃热处理后，试样中A l消失，反应生成了柱状AlN和八面体状MgAl2 O4，此温度下Si尚未参与反应；1200℃热处理后，Si开始反应生成六边形板状的SiC ，镶嵌在镁砂基体中，提高了试样的高温抗折强度和热震后残余抗折强度；1400℃热处理后，试样中除有柱状AlN和八面体状MgAl2 O4生成外，还有较多晶须状SiC和针状β-Si3 N4生成，形成了良好的非氧化物结合，使得材料具有优良的高温力学性能和抗热震性能。
이전용미사、천연린편석묵、매력청、Al분급Si분위주요원료，이열고성분철수지위결합제，혼균후압제성M g O-C재료시양。장시양재담기기분하분별경1000℃×3 h、1200℃×3 h、1400℃×3 h열처리，연구열처리온도대재료물상조성、현미결구급역학성능적영향。결과표명，1000℃열처리후，시양중A l소실，반응생성료주상AlN화팔면체상MgAl2 O4，차온도하Si상미삼여반응；1200℃열처리후，Si개시반응생성륙변형판상적SiC ，양감재미사기체중，제고료시양적고온항절강도화열진후잔여항절강도；1400℃열처리후，시양중제유주상AlN화팔면체상MgAl2 O4생성외，환유교다정수상SiC화침상β-Si3 N4생성，형성료량호적비양화물결합，사득재료구유우량적고온역학성능화항열진성능。
With fused magnesia ,flake graphite and coal tar pitch as main raw materials ,metallic Al and Si powders as additives ,and phenolic resin as binder ,MgO-C refractory specimens were prepared and then heat-treated at 1000 ℃ ,1200 ℃ ,1400 ℃ × 3h respectively under nitrogen atmosphere to study the characteristics of the specimens in phase composition , microstructure and mechanical strength .The results show that after 1000 ℃ heating treatment ,the metallic Al has reacted with C (CO) or N2 ,resulting in the formation of strip-like AlN and octahedral MgAl2 O4 .It is also found that the metallic Si has not taken part in any reaction at this stage .After 1200 ℃ heating treatment , the reaction between Si and C or CO leads to the formation of platelike SiC which is then interlocked into magnesia matrix ,raising the specimen’s modulus of rupture and residual strength after thermal shock test .After 1400 ℃ heating treatment ,besides strip-like AlN and octahedral MgAl2 O4 ,a large amount of SiC whiskers and needlelike β-Si3 N4 are formed within the skeleton structure ,giving the specimen excellent hot modulus of rupture and thermal shock resistance .