CAJ | 학술논문

研究气态条件下原子团簇在完全可控、可重复条件下与CO的反应，可以在分子水平上理解CO的氧化，本综述对这些团簇研究工作进行了一些分析和总结，讨论了团簇研究方法的特点、 CO氧化的新见解以及有待解决的问题。
연구기태조건하원자단족재완전가공、가중복조건하여CO적반응，가이재분자수평상리해CO적양화，본종술대저사단족연구공작진행료일사분석화총결，토론료단족연구방법적특점、 CO양화적신견해이급유대해결적문제。
Carbon monoxide binds to hemoglobin much more tightly than does molecular oxygen, so CO is highly tox-ic to humans and animals. Oxidation of CO into CO2 is a major solution to removal of carbon monoxide in air purifica-tion. CO is also a simple molecule and CO oxidation serves as a prototypical reaction for heterogeneous processes. Atomic clusters composed of limited numbers of atoms are experimentally and theoretically tractable models for hetero-geneous catalysis. During the last decade, a number of publications have been devoted to understanding the CO oxi-dation at a molecular level based on the investigations of gas phase atomic clusters under controlled and well reproduc-ible conditions. In this review, we will go through the reported CO oxidations by gas phase atomic clusters. Advanta-ges, new insights, and problems to be solved involved with the cluster approach for the title reaction will be summa-rized.