有色金属科学与工程
有色金屬科學與工程
유색금속과학여공정
JIANGXI NONFERROUS METALS
2014年
2期
10-14
,共5页
张江生%周康根%姜科%董舒宇%岳楠
張江生%週康根%薑科%董舒宇%嶽楠
장강생%주강근%강과%동서우%악남
土壤%铅%镉%砷%TMT%硫酸铁
土壤%鉛%鎘%砷%TMT%硫痠鐵
토양%연%력%신%TMT%류산철
soils%Pb%Cd%As%TMT%ferric sulfate
以新型TMT(三巯基均三嗪三钠盐)-硫酸铁复配混合物为化学固定剂,考察了其对湖南郴州某重金属污染土壤中铅、镉、砷的固定效果.结果表明,单一使用TMT(含15%(质量分数)TMT的水溶液)为固定剂时,土壤中的有效态铅、镉去除率高于60%,但对砷没有固定效果.使用TMT-硫酸铁复配固定剂时,控制硫酸铁投加量为35.7 g/kg,TMT投加量为0.1 L/kg时,有效态铅、镉去除率达到90%以上.随着土壤含水量的增加,土壤中有效态铅、镉的含量显著降低.当控制硫酸铁投加量为35.7 g/kg,TMT投加量为0.04 L/kg,控制土壤含水量至田间持水量的70%,固定60 d,有效态铅、镉的去除率在80%以上,有效态砷的去除率可达到60%.
以新型TMT(三巰基均三嗪三鈉鹽)-硫痠鐵複配混閤物為化學固定劑,攷察瞭其對湖南郴州某重金屬汙染土壤中鉛、鎘、砷的固定效果.結果錶明,單一使用TMT(含15%(質量分數)TMT的水溶液)為固定劑時,土壤中的有效態鉛、鎘去除率高于60%,但對砷沒有固定效果.使用TMT-硫痠鐵複配固定劑時,控製硫痠鐵投加量為35.7 g/kg,TMT投加量為0.1 L/kg時,有效態鉛、鎘去除率達到90%以上.隨著土壤含水量的增加,土壤中有效態鉛、鎘的含量顯著降低.噹控製硫痠鐵投加量為35.7 g/kg,TMT投加量為0.04 L/kg,控製土壤含水量至田間持水量的70%,固定60 d,有效態鉛、鎘的去除率在80%以上,有效態砷的去除率可達到60%.
이신형TMT(삼구기균삼진삼납염)-류산철복배혼합물위화학고정제,고찰료기대호남침주모중금속오염토양중연、력、신적고정효과.결과표명,단일사용TMT(함15%(질량분수)TMT적수용액)위고정제시,토양중적유효태연、력거제솔고우60%,단대신몰유고정효과.사용TMT-류산철복배고정제시,공제류산철투가량위35.7 g/kg,TMT투가량위0.1 L/kg시,유효태연、력거제솔체도90%이상.수착토양함수량적증가,토양중유효태연、력적함량현저강저.당공제류산철투가량위35.7 g/kg,TMT투가량위0.04 L/kg,공제토양함수량지전간지수량적70%,고정60 d,유효태연、력적거제솔재80%이상,유효태신적거제솔가체도60%.
The stable effect of lead (Pb), cadmium (Cd), arsenic (As) on the heavy metal polluted soils in Chenzhou Hunan with a novel stabilizer of TMT-ferric sulfate are investigated. The results show that the removal rate of the available contents of Pb , Cd in soil is higher than 60 % with the single use of TMT (aqueous solution containing 15 %TMT)as stabilizer, but there is no stable effect on As; the removal rate of the available contents of Pb, Cd in soil is higher than 90 % when TMT-ferric sulfate is used as stabilizer with 35.7 g/kg ferric sulfate and 0.1 L/kg TMT. The available contents of Pb , Cd decreases with the increase of soil water content. The available contents of Pb, Cd decrease more than 80 % and As 60 % with 35.7 g/kg ferric sulfate, 0.04 L/kg TMT and the soil water content is 70%of field capacity lasting 60 days.