宁夏大学学报(自然科学版)
寧夏大學學報(自然科學版)
저하대학학보(자연과학판)
2014年
2期
149-151
,共3页
煤基活性炭%孔结构%炭化%活化
煤基活性炭%孔結構%炭化%活化
매기활성탄%공결구%탄화%활화
coal-based activated carbon%pore structure%carbonization%activation
利用物理吸附分析仪和扫描电子显微镜分别对原料煤成型、炭化和活化过程中的物料形貌和孔结构进行表征研究。结果表明,活性炭制备过程中的炭化和活化工艺是煤基活性炭最为关键的工艺过程之一,对煤基活性炭成孔效果有重要的影响。如果只对物料进行炭化处理而不进行活化工艺,则物料不会形成活性炭所具有的发达的孔隙结构;反之,如果不经过炭化过程而直接进入活化阶段,其结果是尽管可以使活化料产生一定的孔隙结构,然而由于其比表面积和孔容增长有限,达不到预期的吸附效果。物料依次进行适当的炭化和活化过程,产物的孔结构才能得到充分发展,从而才能制备出满足一定需要的活性炭产品。
利用物理吸附分析儀和掃描電子顯微鏡分彆對原料煤成型、炭化和活化過程中的物料形貌和孔結構進行錶徵研究。結果錶明,活性炭製備過程中的炭化和活化工藝是煤基活性炭最為關鍵的工藝過程之一,對煤基活性炭成孔效果有重要的影響。如果隻對物料進行炭化處理而不進行活化工藝,則物料不會形成活性炭所具有的髮達的孔隙結構;反之,如果不經過炭化過程而直接進入活化階段,其結果是儘管可以使活化料產生一定的孔隙結構,然而由于其比錶麵積和孔容增長有限,達不到預期的吸附效果。物料依次進行適噹的炭化和活化過程,產物的孔結構纔能得到充分髮展,從而纔能製備齣滿足一定需要的活性炭產品。
이용물리흡부분석의화소묘전자현미경분별대원료매성형、탄화화활화과정중적물료형모화공결구진행표정연구。결과표명,활성탄제비과정중적탄화화활화공예시매기활성탄최위관건적공예과정지일,대매기활성탄성공효과유중요적영향。여과지대물료진행탄화처리이불진행활화공예,칙물료불회형성활성탄소구유적발체적공극결구;반지,여과불경과탄화과정이직접진입활화계단,기결과시진관가이사활화료산생일정적공극결구,연이유우기비표면적화공용증장유한,체불도예기적흡부효과。물료의차진행괄당적탄화화활화과정,산물적공결구재능득도충분발전,종이재능제비출만족일정수요적활성탄산품。
With automated physisorption and chemisorption analyzer and scanning electron microscope,the material and pore structure was researched during raw coal ’s process of forming, carbonizing,and activating.The research shows that during the preparation process of activated carbon,the vital craft processes of coal-based activated carbon were carbonization and activation,which tremendously affected coal-based activated carbon pore forming effect.The material can not form the well-developed pore structure that activated carbon has unless it is both carbonized and activated.If the material is activated without being carbonized,it can not reach anticipated adsorbing effect because of the limited growth of specific surface area and pore volume,although it can make the activated material create a certain of pore structure.The pore structure of the outcome can be fully developed only when the material is in turn in proper carbonization and activation process,and accordingly the activated carbon products which and meet some kind of demand can be made.