火工品
火工品
화공품
INITIATORS & PYROTECHNICS
2014年
3期
31-34
,共4页
彭儒%朱晨光%陈智杰%张紫浩
彭儒%硃晨光%陳智傑%張紫浩
팽유%주신광%진지걸%장자호
高热剂%超细红磷%薄膜%燃烧温度%燃烧速度
高熱劑%超細紅燐%薄膜%燃燒溫度%燃燒速度
고열제%초세홍린%박막%연소온도%연소속도
Thermite%Ultrafine red phosphorus%Film%Combustion temperature%Combustion speed
采用重结晶的方法,以超细红磷(P)、硝酸钠(NaNO3)为基药,通过梯度设计配方,制成了厚度约为0.70mm、易点燃的薄膜型高热剂,并测定薄膜材料的燃烧时间及燃烧温度;同时,针对烟火药配方中不同组分比例,以及薄膜材料中有无添加聚乙烯醇(PVA)、玻璃纤维(GF)进行了质量燃烧速度、燃烧温度的比较。结果表明:配方为硝酸钠60%、超细红磷39%、添加剂1%的薄膜燃烧温度大于1200℃,质量燃烧速度为0.012 g·cm-2·s-1;添加玻璃纤维和PVA后薄膜的燃烧温度和质量燃烧速度都降低,而且添加PVA配方的燃烧温度和质量燃烧速度降低更加明显。
採用重結晶的方法,以超細紅燐(P)、硝痠鈉(NaNO3)為基藥,通過梯度設計配方,製成瞭厚度約為0.70mm、易點燃的薄膜型高熱劑,併測定薄膜材料的燃燒時間及燃燒溫度;同時,針對煙火藥配方中不同組分比例,以及薄膜材料中有無添加聚乙烯醇(PVA)、玻璃纖維(GF)進行瞭質量燃燒速度、燃燒溫度的比較。結果錶明:配方為硝痠鈉60%、超細紅燐39%、添加劑1%的薄膜燃燒溫度大于1200℃,質量燃燒速度為0.012 g·cm-2·s-1;添加玻璃纖維和PVA後薄膜的燃燒溫度和質量燃燒速度都降低,而且添加PVA配方的燃燒溫度和質量燃燒速度降低更加明顯。
채용중결정적방법,이초세홍린(P)、초산납(NaNO3)위기약,통과제도설계배방,제성료후도약위0.70mm、역점연적박막형고열제,병측정박막재료적연소시간급연소온도;동시,침대연화약배방중불동조분비례,이급박막재료중유무첨가취을희순(PVA)、파리섬유(GF)진행료질량연소속도、연소온도적비교。결과표명:배방위초산납60%、초세홍린39%、첨가제1%적박막연소온도대우1200℃,질량연소속도위0.012 g·cm-2·s-1;첨가파리섬유화PVA후박막적연소온도화질량연소속도도강저,이차첨가PVA배방적연소온도화질량연소속도강저경가명현。
The pyrotechnic P/NaNO3 film was prepared by the recrystallization technology. By gradually decreasing and replacing design formulations, the thermite films with thickness about 0.70mm were tested for combustion time, combustion temperature. The mass combustion rate and combustion temperature of formulations whether adding some PVA and glass fibers or not was compared, and then the combustion reaction mechanism was analyzed. For the formulation composed of sodium nitrate of 60%, red phosphorus of 39%and additive agent of 1%, the combustion temperature was higher than 1 200℃, and the mass combustion rate was 0.012 g·cm-2·s-1. For the formulation added with PVA or glass fiber, the mass combustion rate was decreased, as well as the combustion temperature was reduced, the effect of PVA addition was more obviously.