中国煤炭
中國煤炭
중국매탄
CHINA COAL
2014年
6期
101-105
,共5页
褐煤%中度催化加氢%塑料%热解反应性%黏结指数
褐煤%中度催化加氫%塑料%熱解反應性%黏結指數
갈매%중도최화가경%소료%열해반응성%점결지수
lignite%moderate catalytic hydrogenation%plastic%pyrolysis reactivity%caking index
以元宝山褐煤为研究对象，选用硫酸亚铁作为催化剂，对褐煤进行了非液化中度加氢和催化加氢以及与塑料共混催化加氢增黏改性的试验研究，分析和测定了加氢煤的官能团、热解反应性和黏结性.结果表明，褐煤在反应温度为350℃和10 MPa 的氢压下加氢和催化加氢反应8h后，煤的结构发生了显著变化，煤中脂肪结构显著增多，热解反应性明显提高，煤的黏结性得到显著提高和改善，催化加氢煤的黏结指数从0提高到18?97.在350℃褐煤在催化加氢过程中，聚丙烯的添加弱化了对煤的加氢增黏效果.反应温度为400℃时，催化加氢对煤黏结性的提高影响很小，适宜的加氢反应温度能够使褐煤加氢获得较高的黏结性.
以元寶山褐煤為研究對象，選用硫痠亞鐵作為催化劑，對褐煤進行瞭非液化中度加氫和催化加氫以及與塑料共混催化加氫增黏改性的試驗研究，分析和測定瞭加氫煤的官能糰、熱解反應性和黏結性.結果錶明，褐煤在反應溫度為350℃和10 MPa 的氫壓下加氫和催化加氫反應8h後，煤的結構髮生瞭顯著變化，煤中脂肪結構顯著增多，熱解反應性明顯提高，煤的黏結性得到顯著提高和改善，催化加氫煤的黏結指數從0提高到18?97.在350℃褐煤在催化加氫過程中，聚丙烯的添加弱化瞭對煤的加氫增黏效果.反應溫度為400℃時，催化加氫對煤黏結性的提高影響很小，適宜的加氫反應溫度能夠使褐煤加氫穫得較高的黏結性.
이원보산갈매위연구대상，선용류산아철작위최화제，대갈매진행료비액화중도가경화최화가경이급여소료공혼최화가경증점개성적시험연구，분석화측정료가경매적관능단、열해반응성화점결성.결과표명，갈매재반응온도위350℃화10 MPa 적경압하가경화최화가경반응8h후，매적결구발생료현저변화，매중지방결구현저증다，열해반응성명현제고，매적점결성득도현저제고화개선，최화가경매적점결지수종0제고도18?97.재350℃갈매재최화가경과정중，취병희적첨가약화료대매적가경증점효과.반응온도위400℃시，최화가경대매점결성적제고영향흔소，괄의적가경반응온도능구사갈매가경획득교고적점결성.
Using ferrous sulfate as catalyst,the catalytic moderate nonGliquefaction hydroG genation and addition plastic on hydrogenation processing experiments have been conducted to improve the plastic properties of Yuanbaoshan lignite?The functional groups,pyrolysis reactivity and the indexes of caking property of hydrogenation coal have been measured?The results indicaG ted that under reaction temperature 350℃ and hydrogen pressure 10 MPa for 8 hours,lignite cola structure change obviously?The content of aliphatic hydrocarbon in coal structure and pyrolysis reactivity have been improved significantly?The caking index of hydrogenation coal increasing from 0 to 18?97? The polypropylene addition in catalytic hydrogenation at 350℃has negative effects on lignite plastic property improvement?The caking property of lignite by hydrogenation at 400℃ has not been obviously improved?Appropriate hydrogenation reaction temperature playG scritical role in the caking property improvement.
