化工技术与开发
化工技術與開髮
화공기술여개발
TECHNOLOGY & DVELOPMENT OF CHEMICAL INDUSTRY
2014年
3期
5-6,9
,共3页
李章%李淼%李洪东%戚峰%滕云霞%周徐亮%王寿武
李章%李淼%李洪東%慼峰%滕雲霞%週徐亮%王壽武
리장%리묘%리홍동%척봉%등운하%주서량%왕수무
希夫碱%配合物%红外光谱%合成
希伕堿%配閤物%紅外光譜%閤成
희부감%배합물%홍외광보%합성
schiff base%coordination compound%IR spectra%synthesis
利用乙二胺和亚苄基丙酮反应合成了不饱和化合物（Ph2Me2[14]dieneN4)，再用硼氢化钾与不饱和化合物还原生成饱和的十四元大环化合物（Ph2Me2[14]H2dieneN4)，并用盐酸和氢氧化钠对饱和十四元大环进行提纯，得到纯的十四元大环希夫碱并与乙酸酮反应生成配合物，通过红外光谱进行了表征。
利用乙二胺和亞芐基丙酮反應閤成瞭不飽和化閤物（Ph2Me2[14]dieneN4)，再用硼氫化鉀與不飽和化閤物還原生成飽和的十四元大環化閤物（Ph2Me2[14]H2dieneN4)，併用鹽痠和氫氧化鈉對飽和十四元大環進行提純，得到純的十四元大環希伕堿併與乙痠酮反應生成配閤物，通過紅外光譜進行瞭錶徵。
이용을이알화아변기병동반응합성료불포화화합물（Ph2Me2[14]dieneN4)，재용붕경화갑여불포화화합물환원생성포화적십사원대배화합물（Ph2Me2[14]H2dieneN4)，병용염산화경양화납대포화십사원대배진행제순，득도순적십사원대배희부감병여을산동반응생성배합물，통과홍외광보진행료표정。
The unsaturated Ph2Me2[14]dieneN4( Ⅱ ) compound was formed by ethylene diamine and benzylidene ketones reaction, then the unsaturated Ph2Me2[14]dieneN4( Ⅱ ) was reduced to the saturated fourteen macrocyclic compound Ph2Me2[14] H2dienenN4( Ⅲ ) by potassium borohydride. The saturated fourteen macrocyclic compound was purified with hydrochloric acid and sodium hydroxide. The copper complex was synthesized by this fourteen macrocyclic compound and copper acetate. The title complex was characterized by infrared spectroscopy.
