玻璃
玻璃
파리
GLASS
2014年
4期
40-46
,共7页
磷酸盐玻璃%取代%化学稳定性
燐痠鹽玻璃%取代%化學穩定性
린산염파리%취대%화학은정성
phosphate glass%substitute%chemical durability
在化学组成为40Na2O·60P2O5的基础上，用CaO、MgO取代Na2O或用Al2O3、B2O3和SiO2取代P2O5制备5种磷酸盐玻璃体系，用X射线衍射（XRD）和傅立叶变换红外光谱（FTIR）对玻璃结构进行了表征，并测定了该玻璃体系样品的密度、化学稳定性等基本性质。研究发现，用CaO取代Na2O和Al2O3取代P2O5可以显著改善玻璃的化学稳定性；用SiO2取代P2O5时，玻璃的化学稳定性下降；由于配位问题，B2O3和MgO对磷酸盐玻璃结构与性能的影响出现转折点。
在化學組成為40Na2O·60P2O5的基礎上，用CaO、MgO取代Na2O或用Al2O3、B2O3和SiO2取代P2O5製備5種燐痠鹽玻璃體繫，用X射線衍射（XRD）和傅立葉變換紅外光譜（FTIR）對玻璃結構進行瞭錶徵，併測定瞭該玻璃體繫樣品的密度、化學穩定性等基本性質。研究髮現，用CaO取代Na2O和Al2O3取代P2O5可以顯著改善玻璃的化學穩定性；用SiO2取代P2O5時，玻璃的化學穩定性下降；由于配位問題，B2O3和MgO對燐痠鹽玻璃結構與性能的影響齣現轉摺點。
재화학조성위40Na2O·60P2O5적기출상，용CaO、MgO취대Na2O혹용Al2O3、B2O3화SiO2취대P2O5제비5충린산염파리체계，용X사선연사（XRD）화부립협변환홍외광보（FTIR）대파리결구진행료표정，병측정료해파리체계양품적밀도、화학은정성등기본성질。연구발현，용CaO취대Na2O화Al2O3취대P2O5가이현저개선파리적화학은정성；용SiO2취대P2O5시，파리적화학은정성하강；유우배위문제，B2O3화MgO대린산염파리결구여성능적영향출현전절점。
Based on the chemical composition of 40Na2O·60P2O5,Na2O was replaced by CaO or MgO while P2O5 was replaced by Al2O3, B2O3 or SiO2 respectively. Five kinds of phosphate glass system was prepared,which were characterized using X-ray diffraction( XRD) and Fourier transform infrared spectroscopy( FTIR) . The density, chemical durability of the glass system, as the basic nature, were determined. It was found that the introduction of CaO and Al2O3 can significantly improve the glass chemical stability,while SiO2 destroyed the network structure of phosphate glass. Due to coordination problems, there is a turning point for the influence of B2O3 or MgO on the structure and performance of phosphate glass.
