西南师范大学学报(自然科学版)
西南師範大學學報(自然科學版)
서남사범대학학보(자연과학판)
JOURNAL OF SOUTHWEST CHINA NORMAL UNIVERSITY
2014年
8期
31-35
,共5页
何为媛%杨志敏%陈玉成%李洪亮%王正奎%黄飞%付茂梅%李希希
何為媛%楊誌敏%陳玉成%李洪亮%王正奎%黃飛%付茂梅%李希希
하위원%양지민%진옥성%리홍량%왕정규%황비%부무매%리희희
壳聚糖%铜%吸附%解吸
殼聚糖%銅%吸附%解吸
각취당%동%흡부%해흡
Chitosan%Cu%adsorption%desorption
采用批处理等温吸附解吸试验,研究了初始C u2+浓度、壳聚糖用量、吸附时间、p H值和温度等单因子对壳聚糖吸附C u2+的影响,在此基础上采用正交试验获得最优吸附条件为:壳聚糖用量0.025 g/L ,温度35℃,吸附时间60 min ,初始Cu2+浓度1000 mg/L ,得出最大吸附量为256 mg/g ;因子影响排序由大到小为:壳聚糖用量,温度,初始Cu2+浓度,吸附时间.吸附铜后的壳聚糖,制作壳聚糖载铜灭藻剂(CCA ),其Cu2+释放动力学特征可用Elovich方程、Langmuir方程和二级动力学方程加以描述.pH值和CCA的初始用量对Cu2+释放量有显著影响.
採用批處理等溫吸附解吸試驗,研究瞭初始C u2+濃度、殼聚糖用量、吸附時間、p H值和溫度等單因子對殼聚糖吸附C u2+的影響,在此基礎上採用正交試驗穫得最優吸附條件為:殼聚糖用量0.025 g/L ,溫度35℃,吸附時間60 min ,初始Cu2+濃度1000 mg/L ,得齣最大吸附量為256 mg/g ;因子影響排序由大到小為:殼聚糖用量,溫度,初始Cu2+濃度,吸附時間.吸附銅後的殼聚糖,製作殼聚糖載銅滅藻劑(CCA ),其Cu2+釋放動力學特徵可用Elovich方程、Langmuir方程和二級動力學方程加以描述.pH值和CCA的初始用量對Cu2+釋放量有顯著影響.
채용비처리등온흡부해흡시험,연구료초시C u2+농도、각취당용량、흡부시간、p H치화온도등단인자대각취당흡부C u2+적영향,재차기출상채용정교시험획득최우흡부조건위:각취당용량0.025 g/L ,온도35℃,흡부시간60 min ,초시Cu2+농도1000 mg/L ,득출최대흡부량위256 mg/g ;인자영향배서유대도소위:각취당용량,온도,초시Cu2+농도,흡부시간.흡부동후적각취당,제작각취당재동멸조제(CCA ),기Cu2+석방동역학특정가용Elovich방정、Langmuir방정화이급동역학방정가이묘술.pH치화CCA적초시용량대Cu2+석방량유현저영향.
The batch adsorption-desorption experiments have been conducted to determine the effects of single factors involving initial Cu2+ ,chitosan dosage ,adsorption time ,pH and temperature on adsorption capacity of chitosan on Cu2+ ,and optimal adsorption condition has been achieved through orthogonal test as follows :chitosan dosage 0 .025 g/L ,temperature 35℃ ,adsorption time 60min ,initial Cu2+1 000 mg/L .The impact of factors is ranked in order as chitosan dosage> temperature>initial Cu2+ >adsorption time .T he data of release kinetics of Cu2+from CCA is conformed to Elovich equation ,Langmuir equation as well as second dynamic equation while pH and initial dosage of CCA had obvious impact on release quantity of Cu 2+ .