功能材料
功能材料
공능재료
JOURNAL OF FUNCTIONAL MATERIALS
2014年
13期
13045-13049,13055
,共6页
王朝辉%董彪%高志伟%刘志胜%贺海
王朝輝%董彪%高誌偉%劉誌勝%賀海
왕조휘%동표%고지위%류지성%하해
道路工程%无机阻燃剂%微观表征%阻燃机理
道路工程%無機阻燃劑%微觀錶徵%阻燃機理
도로공정%무궤조연제%미관표정%조연궤리
road engineering%inorganic fire-retardant modifier%structural expressions%retarding mechanism
针对目前某些阻燃剂发烟量大、有毒和成本较高问题,研发了两种新型无机阻燃剂,并制备了无机阻燃改性沥青;借助扫描电镜(SEM)实验和红外光谱(FT-IR)实验,探究了两种阻燃剂与沥青的结合状况以及二者对沥青官能团的影响;通过热重(TG)实验,分析了两种阻燃剂对沥青燃烧过程中热失重变化的影响,探究了两种阻燃改性沥青的作用机理。结果表明,两种新型无机阻燃沥青性能良好;无机阻燃剂颗粒可均匀地分布在沥青中,没有团聚现象,两种阻燃剂各颗粒与沥青具有良好的粘结性;两种新型阻燃剂加入到沥青中,未与沥青形成新的共价键;燃烧过程中无机阻燃改性沥青的热失重大于基础沥青,无机阻燃沥青主要凭借阻燃剂的结合水分挥发以及金属化合物烧结覆盖作用发挥阻燃作用。
針對目前某些阻燃劑髮煙量大、有毒和成本較高問題,研髮瞭兩種新型無機阻燃劑,併製備瞭無機阻燃改性瀝青;藉助掃描電鏡(SEM)實驗和紅外光譜(FT-IR)實驗,探究瞭兩種阻燃劑與瀝青的結閤狀況以及二者對瀝青官能糰的影響;通過熱重(TG)實驗,分析瞭兩種阻燃劑對瀝青燃燒過程中熱失重變化的影響,探究瞭兩種阻燃改性瀝青的作用機理。結果錶明,兩種新型無機阻燃瀝青性能良好;無機阻燃劑顆粒可均勻地分佈在瀝青中,沒有糰聚現象,兩種阻燃劑各顆粒與瀝青具有良好的粘結性;兩種新型阻燃劑加入到瀝青中,未與瀝青形成新的共價鍵;燃燒過程中無機阻燃改性瀝青的熱失重大于基礎瀝青,無機阻燃瀝青主要憑藉阻燃劑的結閤水分揮髮以及金屬化閤物燒結覆蓋作用髮揮阻燃作用。
침대목전모사조연제발연량대、유독화성본교고문제,연발료량충신형무궤조연제,병제비료무궤조연개성력청;차조소묘전경(SEM)실험화홍외광보(FT-IR)실험,탐구료량충조연제여력청적결합상황이급이자대력청관능단적영향;통과열중(TG)실험,분석료량충조연제대력청연소과정중열실중변화적영향,탐구료량충조연개성력청적작용궤리。결과표명,량충신형무궤조연력청성능량호;무궤조연제과립가균균지분포재력청중,몰유단취현상,량충조연제각과립여력청구유량호적점결성;량충신형조연제가입도력청중,미여력청형성신적공개건;연소과정중무궤조연개성력청적열실중대우기출력청,무궤조연력청주요빙차조연제적결합수분휘발이급금속화합물소결복개작용발휘조연작용。
Considering the problem of heavy smoke,toxic,high cost of some flame retardants,two new inorgan-ic flame retardants were developed,and the fire-retardant modified asphalts were prepared;in order to study the internal structure and the flame-retardant mechanism of our new developed flame-retardant asphalt,the combi-nation between flame retardant particles and asphalt were analyzed by scanning electron microscopy (SEM)test and the effect of the flame retardants on the functional groups was studied by infrared spectroscopy (FT-IR) test.The effect of inorganic fire-retardants on the nature of asphalt was analyzed by using TG experiment.The research results showed that the flame retardant effect of the modified asphalt was well;the inorganic fire-re-tardant modifiers can be evenly distributed in asphalt and there was no phenomenon of reunion.FT-IR test shows that there was no covalent generating when the two flame retardants are added into the asphalt.The ther-mal weightlessness of inorganic modified fire-retardant asphalt was greater than that of base asphalt.