功能材料
功能材料
공능재료
JOURNAL OF FUNCTIONAL MATERIALS
2014年
13期
13030-13035
,共6页
王新路%刘俊成%生晗%翟硕彦
王新路%劉俊成%生晗%翟碩彥
왕신로%류준성%생함%적석언
共晶陶瓷%区域熔炼%对流%ACRT%数值模拟
共晶陶瓷%區域鎔煉%對流%ACRT%數值模擬
공정도자%구역용련%대류%ACRT%수치모의
eutectic ceramics%zone-melting%convection%ACRT%numerical simulation
氧化物共晶陶瓷具有优异的超高温力学性能和抗氧化性。为获得具有精细组织的共晶陶瓷,采用有限元法计算模拟了 Al2 O3/MgAl2 O4共晶陶瓷的区域熔炼定向凝固过程。计算结果表明,热重引起的自然对流,呈逆时针环形流,整个凝固过程中流动强度先减小后增大,固液界面呈明显的凹形界面。 ACRT强迫对流的特征为逆时针、顺时针对流胞交替呈现,强度比自然对流大1~2个数量级。施加 ACRT 后,凝固过程中固液界面仍然呈凹形界面,但是凹陷深度显著减小;当坩埚最大转速增大时,对流强度显著增加,固液界面的凹陷深度进一步减小,直至趋近于平界面。
氧化物共晶陶瓷具有優異的超高溫力學性能和抗氧化性。為穫得具有精細組織的共晶陶瓷,採用有限元法計算模擬瞭 Al2 O3/MgAl2 O4共晶陶瓷的區域鎔煉定嚮凝固過程。計算結果錶明,熱重引起的自然對流,呈逆時針環形流,整箇凝固過程中流動彊度先減小後增大,固液界麵呈明顯的凹形界麵。 ACRT彊迫對流的特徵為逆時針、順時針對流胞交替呈現,彊度比自然對流大1~2箇數量級。施加 ACRT 後,凝固過程中固液界麵仍然呈凹形界麵,但是凹陷深度顯著減小;噹坩堝最大轉速增大時,對流彊度顯著增加,固液界麵的凹陷深度進一步減小,直至趨近于平界麵。
양화물공정도자구유우이적초고온역학성능화항양화성。위획득구유정세조직적공정도자,채용유한원법계산모의료 Al2 O3/MgAl2 O4공정도자적구역용련정향응고과정。계산결과표명,열중인기적자연대류,정역시침배형류,정개응고과정중류동강도선감소후증대,고액계면정명현적요형계면。 ACRT강박대류적특정위역시침、순시침대류포교체정현,강도비자연대류대1~2개수량급。시가 ACRT 후,응고과정중고액계면잉연정요형계면,단시요함심도현저감소;당감과최대전속증대시,대류강도현저증가,고액계면적요함심도진일보감소,직지추근우평계면。
Oxide eutectic ceramics was expected to have excellent mechanical property and oxidation resistance at super high temperature.In order to get eutectic ceramics with fine structure,the solidification process of Al2 O3/MgAl2 O4 eutectic ceramics with zone-melting was simulated with finite element.The results showed that the natural convection caused by the thermogravimetric effect was a counterclockwise annular flow,of which flow intensity increases at first,and then decreases as the solidification proceeds.The solid-liquid inter-face keeps a concave one and its concavity decreases at first and then increases.The forced convection caused by ACRT presents that a clockwise flow cell and a counterclockwise one dominate the front of the solid-liquid inter-face alternately,and its intensity was over that of the natural flow by 1-2 orders of magnitude.However the sol-id-liquid interface was still a concave one during the solidification,though the concavity depth decreases obvi-ously.As the crucible maximum rotation rate increases,the forced convection intensity increases,the indenta-tion depth of the solid-liquid interface decreases further.