功能材料
功能材料
공능재료
JOURNAL OF FUNCTIONAL MATERIALS
2014年
8期
8139-8142
,共4页
汪雪梅%王文武%武莉莉%张立祥%冯良桓%张静全%李卫
汪雪梅%王文武%武莉莉%張立祥%馮良桓%張靜全%李衛
왕설매%왕문무%무리리%장립상%풍량환%장정전%리위
Cd1-x Znx Te薄膜%磁控溅射%叠层电池
Cd1-x Znx Te薄膜%磁控濺射%疊層電池
Cd1-x Znx Te박막%자공천사%첩층전지
Cd1-x Znx Te films%magnetron sputtering%layer-built cells
采用双靶共溅射法,分别在不同衬底温度、沉积压强和溅射功率下制备了 Cd1-x Znx Te 多晶薄膜样品,并采用X射线衍射仪、X 射线荧光光谱仪、扫描电子显微镜等方法对制备的 Cd1-x Znx Te 薄膜的结构、成分、形貌和光电学性质进行测试分析。结果表明,300℃衬底温度下制备的Cd1-xZnxTe薄膜成分单一,立方相结构,生长致密,表面颗粒平均大小约50 nm,Cd1-x Znx Te薄膜在(111)晶面的2θ值及晶格常数与Zn组分呈线性关系。Cd1-x Znx Te薄膜的禁带宽度与组分x 值呈线性关系。随着气压从8 Pa降低至1 Pa,Cd1-x Znx Te薄膜的晶粒尺寸增加,生长更加致密。Cd1-xZnxTe薄膜的室温电导率约为8.61×10-11(Ω·cm)-1,呈弱P型。
採用雙靶共濺射法,分彆在不同襯底溫度、沉積壓彊和濺射功率下製備瞭 Cd1-x Znx Te 多晶薄膜樣品,併採用X射線衍射儀、X 射線熒光光譜儀、掃描電子顯微鏡等方法對製備的 Cd1-x Znx Te 薄膜的結構、成分、形貌和光電學性質進行測試分析。結果錶明,300℃襯底溫度下製備的Cd1-xZnxTe薄膜成分單一,立方相結構,生長緻密,錶麵顆粒平均大小約50 nm,Cd1-x Znx Te薄膜在(111)晶麵的2θ值及晶格常數與Zn組分呈線性關繫。Cd1-x Znx Te薄膜的禁帶寬度與組分x 值呈線性關繫。隨著氣壓從8 Pa降低至1 Pa,Cd1-x Znx Te薄膜的晶粒呎吋增加,生長更加緻密。Cd1-xZnxTe薄膜的室溫電導率約為8.61×10-11(Ω·cm)-1,呈弱P型。
채용쌍파공천사법,분별재불동츤저온도、침적압강화천사공솔하제비료 Cd1-x Znx Te 다정박막양품,병채용X사선연사의、X 사선형광광보의、소묘전자현미경등방법대제비적 Cd1-x Znx Te 박막적결구、성분、형모화광전학성질진행측시분석。결과표명,300℃츤저온도하제비적Cd1-xZnxTe박막성분단일,립방상결구,생장치밀,표면과립평균대소약50 nm,Cd1-x Znx Te박막재(111)정면적2θ치급정격상수여Zn조분정선성관계。Cd1-x Znx Te박막적금대관도여조분x 치정선성관계。수착기압종8 Pa강저지1 Pa,Cd1-x Znx Te박막적정립척촌증가,생장경가치밀。Cd1-xZnxTe박막적실온전도솔약위8.61×10-11(Ω·cm)-1,정약P형。
Cd1-x Znx Te crystalline thin films were deposited by magnetron co-sputtering with ZnTe and CdTe targets at different temperatures,pressure and sputtering power.The properties of films were characterized by SEM,XRD and XRF to investigate the structure,composition and surface morphology.The optical and electri-cal properties of the films were also investigated.The results showed that the films prepared at 300 ℃ were cu-bic phase with a dense surface and an average particle size of about 50 nm.A linear relationship was obtained between Zn composition and lattice constant as well as Zn composition and the band gap of the film.With the decrease of the pressure from 8 to 1 Pa the grain size increased and a denser surface was appeared.The as-de-posited Cd1-xZnxTe polycrystalline films showed weak p-type conduction with the conductivity of about 8.61× 10-11 (Ω·cm)-1 at room temperature.