CAJ | 학술논문

探讨采用微波辅助合成尾式卟啉（p-BrTMOPP）的制备工艺及其影响因素。以吡咯、对羟基苯甲醛和对甲氧基苯甲醛为原料，以丙酸为溶剂，制备得到p-HTMOPP；以1,4-二溴丁烷为原料，微波辅助加热条件下制备得到目标化合物尾式卟啉p-BrTMOPP；目标产物经过UV-vis、IR、ESI-MS等方法表征。在90℃、DMF溶剂条件下微波辐射加热30min，快速高效得到目标化合物，反应产率89.2%。和传统加热方法相比较，微波辅助合成尾式卟啉化合物明显缩短了反应时间，提高了反应效率。
탐토채용미파보조합성미식계람（p-BrTMOPP）적제비공예급기영향인소。이필각、대간기분갑철화대갑양기분갑철위원료，이병산위용제，제비득도p-HTMOPP；이1,4-이추정완위원료，미파보조가열조건하제비득도목표화합물미식계람p-BrTMOPP；목표산물경과UV-vis、IR、ESI-MS등방법표정。재90℃、DMF용제조건하미파복사가열30min，쾌속고효득도목표화합물，반응산솔89.2%。화전통가열방법상비교，미파보조합성미식계람화합물명현축단료반응시간，제고료반응효솔。
The synthesis of a novel tailed porphyrin(p-BrTMOPP) is studied. The p-HTMOPP was prepared from pyrrole,p-hydroxybenzaldehyde and p-methoxybenzaldehyde in propionic acid solution,and then p-HTMOPP and 1,4-dibromobutane were mixed in DMF solution to synthetize p-BrTMOPP by using microwave-assisted synthesis technology. The target compound, p-BrTMOPP, was characterized by using UV-vis, IR,and ESI-MS spectra. The p-BrTMOPP was prepared from p-HTMOPP and 1,4-dibromobutane in DMF solution at 90℃for 30 min under microwave-assisted with a yield of 89.2%. A tailed porphyrin was synthesized under microwave-assisted,and with less time and higher efficiency compared with the conventional method.