当代化工
噹代化工
당대화공
CONTEMPORARY CHEMICAL INDUSTRY
2014年
4期
591-593
,共3页
陈建华%员荣平%齐士成%江盛玲%张孝阿%吕亚非
陳建華%員榮平%齊士成%江盛玲%張孝阿%呂亞非
진건화%원영평%제사성%강성령%장효아%려아비
超分子聚合物%自愈合行为%非共价键相互作用
超分子聚閤物%自愈閤行為%非共價鍵相互作用
초분자취합물%자유합행위%비공개건상호작용
Supramolecular polymers%Self-healing behavior%Non-covalent bond interactions
由于非共价键的选择性、可逆性和动态性,超分子聚合物非常适合作为自愈合材料应用,体现了感知和响应功能的智能特征。超分子聚合物的自愈合机理是通过非共价键相互作用实现的,即超分子结构的形成与解离。综述氢键型、?-?堆叠型、金属配位型、拓扑聚合物等类型的超分子聚合物的自愈合行为。
由于非共價鍵的選擇性、可逆性和動態性,超分子聚閤物非常適閤作為自愈閤材料應用,體現瞭感知和響應功能的智能特徵。超分子聚閤物的自愈閤機理是通過非共價鍵相互作用實現的,即超分子結構的形成與解離。綜述氫鍵型、?-?堆疊型、金屬配位型、拓撲聚閤物等類型的超分子聚閤物的自愈閤行為。
유우비공개건적선택성、가역성화동태성,초분자취합물비상괄합작위자유합재료응용,체현료감지화향응공능적지능특정。초분자취합물적자유합궤리시통과비공개건상호작용실현적,즉초분자결구적형성여해리。종술경건형、?-?퇴첩형、금속배위형、탁복취합물등류형적초분자취합물적자유합행위。
Due to the selectivity, reversibility and dynamics of the non-covalent bond, the supramolecular polymer is well suited for application as a self-healing material with smart features, like sense and response capabilities. The self-healing mechanism of supramolecular polymers is achieved through non-covalent bond interactions, so-called the formation and dissociation of supramolecular structure. In this paper,the self-healing behavior of supramolecular polymers was introduced, such as hydrogen bonding supramolecular polymers,?-?stacking supramolecular polymers, metal coordination type supramolecular polymers and topological type supramolecular polymers.