天津科技大学学报
天津科技大學學報
천진과기대학학보
JOURNAL OF TIANJIN UNIVERSITY OF SCIENCE & TECHNOLOGY
2014年
2期
25-29
,共5页
木质活性炭纤维%纳米TiO2%负载%光催化%甲醛
木質活性炭纖維%納米TiO2%負載%光催化%甲醛
목질활성탄섬유%납미TiO2%부재%광최화%갑철
wooden activated carbon fiber%nano-TiO2%loading%photocatalyst%formaldehyde
以杉木木粉经苯酚液化、熔融纺丝、固化处理、二氧化碳活化后获得的木质活性炭纤维为载体,采用溶胶-凝胶法制备木质活性炭纤维负载纳米 TiO2(WACFs/TiO2)光催化复合材料.研究光照时间、WACFs/TiO2催化剂用量、纳米TiO2负载量和初始甲醛质量浓度对WACFs/TiO2降解甲醛效果的影响.结果表明:随着光照时间、催化剂用量、初始甲醛质量浓度的增加,WACFs/TiO2对甲醛的降解率逐渐增加,但催化剂用量对甲醛降解率的影响相对较小;随 TiO2负载量的增多,WACFs/TiO2对甲醛的降解率呈现先增加后减小的趋势.当光照时间7,h、催化剂用量0.5,g、纳米 TiO2负载量29.89%、初始甲醛质量浓度8.82,mg/L时,WACFs/TiO2对甲醛的降解率达到92.33%.
以杉木木粉經苯酚液化、鎔融紡絲、固化處理、二氧化碳活化後穫得的木質活性炭纖維為載體,採用溶膠-凝膠法製備木質活性炭纖維負載納米 TiO2(WACFs/TiO2)光催化複閤材料.研究光照時間、WACFs/TiO2催化劑用量、納米TiO2負載量和初始甲醛質量濃度對WACFs/TiO2降解甲醛效果的影響.結果錶明:隨著光照時間、催化劑用量、初始甲醛質量濃度的增加,WACFs/TiO2對甲醛的降解率逐漸增加,但催化劑用量對甲醛降解率的影響相對較小;隨 TiO2負載量的增多,WACFs/TiO2對甲醛的降解率呈現先增加後減小的趨勢.噹光照時間7,h、催化劑用量0.5,g、納米 TiO2負載量29.89%、初始甲醛質量濃度8.82,mg/L時,WACFs/TiO2對甲醛的降解率達到92.33%.
이삼목목분경분분액화、용융방사、고화처리、이양화탄활화후획득적목질활성탄섬유위재체,채용용효-응효법제비목질활성탄섬유부재납미 TiO2(WACFs/TiO2)광최화복합재료.연구광조시간、WACFs/TiO2최화제용량、납미TiO2부재량화초시갑철질량농도대WACFs/TiO2강해갑철효과적영향.결과표명:수착광조시간、최화제용량、초시갑철질량농도적증가,WACFs/TiO2대갑철적강해솔축점증가,단최화제용량대갑철강해솔적영향상대교소;수 TiO2부재량적증다,WACFs/TiO2대갑철적강해솔정현선증가후감소적추세.당광조시간7,h、최화제용량0.5,g、납미 TiO2부재량29.89%、초시갑철질량농도8.82,mg/L시,WACFs/TiO2대갑철적강해솔체도92.33%.
Wooden activated carbon fibers loaded nano-TiO2(WACFs/TiO2)was prepared by sol-gel method and with WACFs as the support which was obtained from the phenolated Chinese fir after phenol liquefaction,melt spinning,and curing treatment through CO2,activation. The effects of lighting time,WACFs/TiO2,doses,loading rate of nano-TiO2and initial formaldehyde concentration on the degradation rate of formaldehyde with WACFs/TiO2 were studied. The results showed that with the increase of lighting time,WACFs/TiO2 dose and initial formaldehyde concentration,the degradation rate of formaldehyde gradually increased. With the increase of the loading rate of nano-TiO2,the degradation rate of formal-dehyde first increased and then decreased. When the lighting time was 7 h,the WACFs/TiO2 dose 0.5,g,the loading rate of nano-TiO229.89% and the initial formaldehyde concentration 8.82,mg/L,the degradation rate of formaldehyde reached 92.33%.