CAJ | 학술논문

在无需进行物质分离的条件下，利用紫外-可见分光光度计分别测定Fe2+、Fe3+、H2O2各自不同浓度下的吸光度，以及三者混合后不同波长下的全扫描吸收强度，研究 Fenton 氧化反应过程中络合物形成的规律。实验结果表明：在排除降解底物影响的情况下，Fenton氧化反应过程中产生了一种铁系络合物，在所考察的整个波段(190～500 nm)内呈现出较大的吸光度，从而验证了 Fenton 氧化反应过程中络合物的存在，其浓度是随着双氧水的浓度而变化，为阐明Fenton氧化反应过程中羟基自由基产生的机理提供了有力的基础数据。
재무수진행물질분리적조건하，이용자외-가견분광광도계분별측정Fe2+、Fe3+、H2O2각자불동농도하적흡광도，이급삼자혼합후불동파장하적전소묘흡수강도，연구 Fenton 양화반응과정중락합물형성적규률。실험결과표명：재배제강해저물영향적정황하，Fenton양화반응과정중산생료일충철계락합물，재소고찰적정개파단(190～500 nm)내정현출교대적흡광도，종이험증료 Fenton 양화반응과정중락합물적존재，기농도시수착쌍양수적농도이변화，위천명Fenton양화반응과정중간기자유기산생적궤리제공료유력적기출수거。
Absorbance of different concentrations of Fe2+,Fe3+ and H2O2 was investigated individually by using UV-Visible spectrophotometer without separating the substances in the solution. With the changes of UV-Vis spectra of the mixture of these three substances throughout the whole reaction,the law of complex formation was studied. The result shows that iron-based complex is found without substrate in Fenton reaction,which has great absorbance across the entire band(190-500,nm)examined. Thus the existence of complex in Fenton oxidation process is verified. Its concentration varies with the change of concentration of hydrogen peroxide.This research has provided a strong foundation for further studiesof the reaction mechanism of hydroxyl radical in Fenton oxidation process.