光谱学与光谱分析
光譜學與光譜分析
광보학여광보분석
SPECTROSCOPY AND SPECTRAL ANALYSIS
2014年
5期
1348-1351
,共4页
连续投影算法%最小二乘支持向量机%土壤%有机质%速效钾
連續投影算法%最小二乘支持嚮量機%土壤%有機質%速效鉀
련속투영산법%최소이승지지향량궤%토양%유궤질%속효갑
Successive projections algorithm%LS-SVM%Soil%Organic matter%Available potassium
应用可见/短波近红外光谱分析测量土壤有机质和速效钾含量。光谱预处理包括平滑,标准归一化,多元散射校正和平滑结合一阶导数,以消除系统噪声和外部干扰,分别应用偏最小二乘和最小二乘支持向量机方法建立校正模型,模型的输入为基于连续投影算法得到的特征波长。比较显示基于连续投影算法得到的特征波长为输入的最小二乘支持向量机优于偏最小二乘法建模。模型评价指标由相关系数和预测均方误差表示。有机质的相关系数和预测均方误差分别0.8602和2.98,速效钾为0.7305和15.78。表明基于连续投影算法可见/短波近红外光谱利用最小二乘支持向量机建模,可以作为一个精确的土壤有机质和速效钾的测定方法。
應用可見/短波近紅外光譜分析測量土壤有機質和速效鉀含量。光譜預處理包括平滑,標準歸一化,多元散射校正和平滑結閤一階導數,以消除繫統譟聲和外部榦擾,分彆應用偏最小二乘和最小二乘支持嚮量機方法建立校正模型,模型的輸入為基于連續投影算法得到的特徵波長。比較顯示基于連續投影算法得到的特徵波長為輸入的最小二乘支持嚮量機優于偏最小二乘法建模。模型評價指標由相關繫數和預測均方誤差錶示。有機質的相關繫數和預測均方誤差分彆0.8602和2.98,速效鉀為0.7305和15.78。錶明基于連續投影算法可見/短波近紅外光譜利用最小二乘支持嚮量機建模,可以作為一箇精確的土壤有機質和速效鉀的測定方法。
응용가견/단파근홍외광보분석측량토양유궤질화속효갑함량。광보예처리포괄평활,표준귀일화,다원산사교정화평활결합일계도수,이소제계통조성화외부간우,분별응용편최소이승화최소이승지지향량궤방법건립교정모형,모형적수입위기우련속투영산법득도적특정파장。비교현시기우련속투영산법득도적특정파장위수입적최소이승지지향량궤우우편최소이승법건모。모형평개지표유상관계수화예측균방오차표시。유궤질적상관계수화예측균방오차분별0.8602화2.98,속효갑위0.7305화15.78。표명기우련속투영산법가견/단파근홍외광보이용최소이승지지향량궤건모,가이작위일개정학적토양유궤질화속효갑적측정방법。
Visible and short wave infrared spectroscopy (Vis/SW-NIRS) was investigated in the present study for measurement of soil organic matter (OM) and available potassium (K) .Four types of pretreatments including smoothing ,SNV ,MSC and SG smoothing+first derivative were adopted to eliminate the system noises and external disturbances .Then partial least squares re-gression (PLSR) and least squares-support vector machine (LS-SVM ) models were implemented for calibration models .The LS-SVM model was built by using characteristic wavelength based on successive projections algorithm (SPA) .Simultaneously ,the performance of LS-SVM models was compared with PLSR models .The results indicated that LS-SVM models using characteris-tic wavelength as inputs based on SPA outperformed PLSR models .The optimal SPA-LS-SVM models were achieved ,and the correlation coefficient (r) ,and RMSEP were 0.860 2 and 2.98 for OM and 0.730 5 and 15.78 for K ,respectively .The results indicated that visible and short wave near infrared spectroscopy (Vis/SW-NIRS ) (325 ~ 1 075 nm ) combined with LS-SVM based on SPA could be utilized as a precision method for the determination of soil properties .