光谱学与光谱分析
光譜學與光譜分析
광보학여광보분석
SPECTROSCOPY AND SPECTRAL ANALYSIS
2014年
5期
1249-1252
,共4页
遥测%天然气泄漏%静态傅里叶变换干涉系统%浓度程长积
遙測%天然氣洩漏%靜態傅裏葉變換榦涉繫統%濃度程長積
요측%천연기설루%정태부리협변환간섭계통%농도정장적
Remote detection%Gas leakage%Static Fourier transform interferometer system%Concentration-path-length product
为快速地、大范围地对天然气管道进行泄漏监测,设计了基于静态傅里叶变换干涉系统的甲烷气体浓度遥测系统。采用对准甲烷分子吸收峰的红外光源照射被测区域,再由聚光准直系统和干涉模块完成干涉条纹的获取。最后,通过多特征波长光谱分析算法计算被测区域的浓度程长积,进而反演相应的甲烷浓度。通过HITRAN光谱数据库选择了1.65μm的主特征吸收峰,从而光源使用1.65μm的DFB激光器。为了在不增加系统硬件结构的基础上提高检测精度及稳定性,引入辅助波长求解吸光度比值,进而通过多特征波长比例运算的方法获得被测气体的浓度程长积。实验针对泄漏速度恒定的标准甲烷液化气罐检测,采用PN1000型便携式甲烷检测仪的检测数据作为标准数据与本系统的测试数据进行对比,测试距离分别为100,200和500 m。实验结果显示,甲烷浓度检测值在泄漏一段时间稳定后,系统检测值也基本保持稳定。对100 m的检测距离而言,浓度程长积的检测误差小于1.0%。随着测试距离的增大,检测误差也相应的增大,距离500 m的检测误差小于4.5%。总之,在气体泄露稳定后系统检测误差均小于5.0%,满足野外天然气泄漏遥测要求,该方法采用差分思想,在求解吸光度比率的过程中将误差消除,降低了外界干扰造成的误差,从而提高系统的检测精度及稳定性。
為快速地、大範圍地對天然氣管道進行洩漏鑑測,設計瞭基于靜態傅裏葉變換榦涉繫統的甲烷氣體濃度遙測繫統。採用對準甲烷分子吸收峰的紅外光源照射被測區域,再由聚光準直繫統和榦涉模塊完成榦涉條紋的穫取。最後,通過多特徵波長光譜分析算法計算被測區域的濃度程長積,進而反縯相應的甲烷濃度。通過HITRAN光譜數據庫選擇瞭1.65μm的主特徵吸收峰,從而光源使用1.65μm的DFB激光器。為瞭在不增加繫統硬件結構的基礎上提高檢測精度及穩定性,引入輔助波長求解吸光度比值,進而通過多特徵波長比例運算的方法穫得被測氣體的濃度程長積。實驗針對洩漏速度恆定的標準甲烷液化氣罐檢測,採用PN1000型便攜式甲烷檢測儀的檢測數據作為標準數據與本繫統的測試數據進行對比,測試距離分彆為100,200和500 m。實驗結果顯示,甲烷濃度檢測值在洩漏一段時間穩定後,繫統檢測值也基本保持穩定。對100 m的檢測距離而言,濃度程長積的檢測誤差小于1.0%。隨著測試距離的增大,檢測誤差也相應的增大,距離500 m的檢測誤差小于4.5%。總之,在氣體洩露穩定後繫統檢測誤差均小于5.0%,滿足野外天然氣洩漏遙測要求,該方法採用差分思想,在求解吸光度比率的過程中將誤差消除,降低瞭外界榦擾造成的誤差,從而提高繫統的檢測精度及穩定性。
위쾌속지、대범위지대천연기관도진행설루감측,설계료기우정태부리협변환간섭계통적갑완기체농도요측계통。채용대준갑완분자흡수봉적홍외광원조사피측구역,재유취광준직계통화간섭모괴완성간섭조문적획취。최후,통과다특정파장광보분석산법계산피측구역적농도정장적,진이반연상응적갑완농도。통과HITRAN광보수거고선택료1.65μm적주특정흡수봉,종이광원사용1.65μm적DFB격광기。위료재불증가계통경건결구적기출상제고검측정도급은정성,인입보조파장구해흡광도비치,진이통과다특정파장비례운산적방법획득피측기체적농도정장적。실험침대설루속도항정적표준갑완액화기관검측,채용PN1000형편휴식갑완검측의적검측수거작위표준수거여본계통적측시수거진행대비,측시거리분별위100,200화500 m。실험결과현시,갑완농도검측치재설루일단시간은정후,계통검측치야기본보지은정。대100 m적검측거리이언,농도정장적적검측오차소우1.0%。수착측시거리적증대,검측오차야상응적증대,거리500 m적검측오차소우4.5%。총지,재기체설로은정후계통검측오차균소우5.0%,만족야외천연기설루요측요구,해방법채용차분사상,재구해흡광도비솔적과정중장오차소제,강저료외계간우조성적오차,종이제고계통적검측정도급은정성。
In order to be able to quickly ,to a wide range of natural gas pipeline leakage monitoring ,the remote detection system for concentration of methane gas was designed based on static Fourier transform interferometer .The system used infrared light , which the center wavelength was calibrated to absorption peaks of methane molecules ,to irradiated tested area ,and then got the interference fringes by converging collimation system and interference module .Finally ,the system calculated the concentration-path-length product in tested area by multi-wavelength characteristics spectrum analysis algorithm ,furthermore the inversion of the corresponding concentration of methane .By HITRAN spectrum database ,Selected wavelength position of 1.65 μm as the main characteristic absorption peaks ,thereby using 1.65 μm DFB laser as the light source .In order to improve the detection ac-curacy and stability without increasing the hardware configuration of the system ,solved absorbance ratio by the auxiliary wave-length ,and then get concentration-path-length product of measured gas by the method of the calculation proportion of multi-wavelength characteristics .The measurement error from external disturbance is caused by this innovative approach ,and it is more similar to a differential measurement .It will eliminate errors in the process of solving the ratio of multi-wavelength charac-teristics ,and can improve accuracy and stability of the system .The infrared absorption spectrum of methane is constant ,the ra-tio of absorbance of any two wavelengths by methane is also constant .The error coefficients produced by the system is the same when it received the same external interference ,so the measured noise of the system can be effectively reduced by the ratio meth-od .Experimental tested standards methane gas tank with leaking rate constant .Using the tested data of PN1000 type portable methane detector as the standard data ,and were compared to the tested data of the system ,while tested distance of the system were 100 ,200 and 500 m .Experimental results show that the methane concentration detected value was stable after a certain time leakage ,the concentration-path-length product value of the system was stable .For detection distance of 100 m ,the detec-tion error of the concentration-path-length product was less than 1.0% .With increasing distance from tested area ,the detection error is increased correspondingly .When the distance was 500 m ,the detection error was less than 4.5% .In short ,the detected error of the system is less than 5.0% after the gas leakage stable ,to meet the requirements of the field of natural gas leakage re-mo te sensing .