CAJ | 학술논문

随着本质安全研究的深入，道化学评价方法中物质系数MF的计算已不能准确描述反应物本身的热风险大小。在道化学评价方法中引入热风险概念，比较热危险性评价方法和道化学评价方法间相异点；以六甲基磷酰三胺工艺为研究对象，用DSC量热仪对反应物进行分析得出放热速率q、反应波峰峰值、单位质量的反应焓Hr ，对采集的工艺参数用热力学理论外推法、基因贡献法得出活化能E、比热容CP 并以此求出最大反应失效时间TMRad、绝热温升Qad、物质系数MF值以及工艺单元中物料量。得出最大反应失效时间与物质系数MF间具有相关性，道化学评价方法对因失效反应引发二次反应的热风险评估也适用。
수착본질안전연구적심입，도화학평개방법중물질계수MF적계산이불능준학묘술반응물본신적열풍험대소。재도화학평개방법중인입열풍험개념，비교열위험성평개방법화도화학평개방법간상이점；이륙갑기린선삼알공예위연구대상，용DSC량열의대반응물진행분석득출방열속솔q、반응파봉봉치、단위질량적반응함Hr ，대채집적공예삼수용열역학이론외추법、기인공헌법득출활화능E、비열용CP 병이차구출최대반응실효시간TMRad、절열온승Qad、물질계수MF치이급공예단원중물료량。득출최대반응실효시간여물질계수MF간구유상관성，도화학평개방법대인실효반응인발이차반응적열풍험평고야괄용。
With the developmentof safety research , material factor ( MF value ) of Dow chemical evaluation method can not accurately describe the size of thermal risk .The difference between thermal hazard evaluation method and Dow chemical evaluation method was analyzed by introducing thermal rick concept in Dow chemical evalution .DSC calorimeter was used to applysis the reactant so as to obtain heat release rate q , reaction wave peak and reaction en-thalpy Hr .The thermodynamic theory extrapolation and group contribution method were applied to analyze the mea-surred process parameters , activation energy E and specific heat capacity CP were obtained , then the maximum re-sponse time to failure TMR ad , adiabatic temperature rise Qad, material factor MF and the amount of material in the process unit were found out .It showed that the maximum response time to failure is related with MF , and Dow chemical evaluation method is useful for thermal risk assessment with secondary reaction caused by failure reaction .