CAJ | 학술논문

采用原位复合法和界面聚合法分别制备了纤维状的聚苯胺/乙炔炭黑复合材料和聚苯胺,讨论了复合电极中聚苯胺含量对超级电容器电化学性能的影响。研究表明,复合电极材料中聚苯胺的含量不是影响其电化学性能的决定性因素。聚苯胺/乙炔炭黑复合电极(直径约200 nm)在5 mA/cm2和1 mol/L 的H2 SO4溶液中首次充放电单电极比电容高达432 F/g,该值比聚苯胺含量高的复合电极和直径相近纯聚苯胺电极的单极比电容值354和416 F/g都高。
채용원위복합법화계면취합법분별제비료섬유상적취분알/을결탄흑복합재료화취분알,토론료복합전겁중취분알함량대초급전용기전화학성능적영향。연구표명,복합전겁재료중취분알적함량불시영향기전화학성능적결정성인소。취분알/을결탄흑복합전겁(직경약200 nm)재5 mA/cm2화1 mol/L 적H2 SO4용액중수차충방전단전겁비전용고체432 F/g,해치비취분알함량고적복합전겁화직경상근순취분알전겁적단겁비전용치354화416 F/g도고。
Polyaniline/carbon black fibrous composites and fibrous polyaniline were respectively prepared via in-suit chemical oxidization polymerization and interfacial polymerization.The influence of polyaniline mass frac-tion in composite electrodes was discussed on the electrochemical performance of the electrodes.The results show that the mass fraction of polyaniline in the composite electrode materials was not the decisive factor for the electrochemical performance.The specific capacitance of the composites fibre (It’s diameter was about 200 nm) with primary nano-particles was up to 432 F/g at 5 mA/cm2 in 1 mol/L H2 SO4 electrolyte.The value was high-er than those of the composites (354 F/g)containing higher the mass fraction polyaniline and polyaniline fibre (416 F/g).