CAJ | 학술논문

制备和表征了胺基修饰的超高交联聚苯乙烯吸附树脂，结构特征研究表明树脂具有较高的比表面、丰富的微孔和碱性极性基团等优点。比较研究了树脂对水体系中两类芳香酚（苯酚和邻硝基苯酚）的静态吸附性能，结果表明吸附过程呈现放热特征，树脂对疏水性更强的邻硝基苯酚具有更优的吸附性能。吸附平衡数据均可采用Langmuir和Freundlich吸附等温方程进行较好的拟合，结果表明树脂对两类芳香酚的吸附均为优惠吸附，且呈现出物理吸附为主，弱化学吸附为辅的吸附机理。
제비화표정료알기수식적초고교련취분을희흡부수지，결구특정연구표명수지구유교고적비표면、봉부적미공화감성겁성기단등우점。비교연구료수지대수체계중량류방향분（분분화린초기분분）적정태흡부성능，결과표명흡부과정정현방열특정，수지대소수성경강적린초기분분구유경우적흡부성능。흡부평형수거균가채용Langmuir화Freundlich흡부등온방정진행교호적의합，결과표명수지대량류방향분적흡부균위우혜흡부，차정현출물리흡부위주，약화학흡부위보적흡부궤리。
The hypercrosslinked polystyrene adsorbent was prepared By Friedel-Crafts post-crosslinking reaction with Trimethylamine. According to the adsorption experiment in aqueous solution, the adsorption capacity of o-nitrophenol with high hydrophobicity is bigger than that of phenol. Fitting data shows that adsorption of phenol and o-nitrophenol on resin fitted well to Langmuir and Freundlich model. The adsorption mechanism technology is mainly based on chemical adsorption, and partially based on physical one.