陕西科技大学学报(自然科学版)
陝西科技大學學報(自然科學版)
협서과기대학학보(자연과학판)
JOURNAL OF SHAANXI UNIVERSITY OF SCIENCE & TECHNOLOGY
2014年
3期
15-19
,共5页
林涛%李雪%徐永建%朱振峰%张鼎军
林濤%李雪%徐永建%硃振峰%張鼎軍
림도%리설%서영건%주진봉%장정군
钠基膨润土%铝盐%制备%绿液%除硅
鈉基膨潤土%鋁鹽%製備%綠液%除硅
납기팽윤토%려염%제비%록액%제규
Na-bentonite%aluminum salt%preparation%green liquor%silicate removal
以钠基膨润土为原料,通过添加铝盐为改性剂,制备出了一种新型高效绿液除硅剂,其硅吸附效率最高可达90%左右。并以竹浆绿液的硅吸附率和p H变化为标准,研究了该种改性膨润土的制备工艺。其最佳工艺条件为:钠基膨润土与铝盐的质量比为1∶4;添加顺序先将钠基膨润土与水混合,再加入铝盐,加水量为66mL/1g钠基膨润土;搅拌时间为2h,搅拌速率为1200 r/min ;反应温度为室温,静置分离12 h ,105℃干燥,研磨,过200目筛。
以鈉基膨潤土為原料,通過添加鋁鹽為改性劑,製備齣瞭一種新型高效綠液除硅劑,其硅吸附效率最高可達90%左右。併以竹漿綠液的硅吸附率和p H變化為標準,研究瞭該種改性膨潤土的製備工藝。其最佳工藝條件為:鈉基膨潤土與鋁鹽的質量比為1∶4;添加順序先將鈉基膨潤土與水混閤,再加入鋁鹽,加水量為66mL/1g鈉基膨潤土;攪拌時間為2h,攪拌速率為1200 r/min ;反應溫度為室溫,靜置分離12 h ,105℃榦燥,研磨,過200目篩。
이납기팽윤토위원료,통과첨가려염위개성제,제비출료일충신형고효록액제규제,기규흡부효솔최고가체90%좌우。병이죽장록액적규흡부솔화p H변화위표준,연구료해충개성팽윤토적제비공예。기최가공예조건위:납기팽윤토여려염적질량비위1∶4;첨가순서선장납기팽윤토여수혼합,재가입려염,가수량위66mL/1g납기팽윤토;교반시간위2h,교반속솔위1200 r/min ;반응온도위실온,정치분리12 h ,105℃간조,연마,과200목사。
A novel and efficient silicate removal adsorbent was prepared from Na-bentonite and the aluminum salt used as the modified agent .The adsorption rate of aluminum salt modified bentonite could reach at about 90% .T he preparation process of modified bentonite was explored as the standard of the adsorption and change rate in green liquor .The optimum conditions were that mass ratio between Na-bentonite and aluminum salt was 1∶4;the order of adding raw materials was that Na-bentonite was mixed with water at first ,then ,aluminum salt was added;the water addition was 66 mL/1 g of Na-bentonite;stirring time was 2 h;stir-ring speed was 1 200 r/min ;reaction temperature was at room temperature ;separate time was 12 h;dried at 105 ℃ and screened through 200 mesh .