CAJ | 학술논문

以2-氨甲基吡啶为配体与醋酸锌反应合成了一种新型锌金属配合物[Zn( AMPy)2(OAc)]2·[ Zn( OAc)4]( AMPy=2-氨甲基吡啶),通过核磁共振谱、红外光谱、元素分析和X射线单晶衍射对其结构进行了表征.晶体结构显示,该配合物属于三斜晶系,空间群为 P1,晶胞参数为 a=1.07360(19) nm, b=1.2491(2) nm, c=1.8976(3) nm,α=83.809(2)°,β=89.595(2)°,γ=65.708(2)°, V=2.3039(7) nm3, Z=2；配合物分子由3个不同的配位Zn离子通过分子内氢键连成一个完整的分子,分子间氢键再将其连成一个二维网状结构.研究了该金属配合物在Henry催化反应方面的性能,并优化出最佳催化条件.
이2-안갑기필정위배체여작산자반응합성료일충신형자금속배합물[Zn( AMPy)2(OAc)]2·[ Zn( OAc)4]( AMPy=2-안갑기필정),통과핵자공진보、홍외광보、원소분석화X사선단정연사대기결구진행료표정.정체결구현시,해배합물속우삼사정계,공간군위 P1,정포삼수위 a=1.07360(19) nm, b=1.2491(2) nm, c=1.8976(3) nm,α=83.809(2)°,β=89.595(2)°,γ=65.708(2)°, V=2.3039(7) nm3, Z=2；배합물분자유3개불동적배위Zn리자통과분자내경건련성일개완정적분자,분자간경건재장기련성일개이유망상결구.연구료해금속배합물재Henry최화반응방면적성능,병우화출최가최화조건.
A novel zinc metal complex [ Zn ( AMPy ) 2 ( OAc ) ] 2 [ Zn ( OAc ) 4 ] [ AMPy=2-( aminomethyl ) pyridine] was synthesized by the reaction of zinc acetate to 2-( aminomethyl) pyridine ligand. The structure of the complex was characterized by 1 H NMR, IR, elemental analysis and X-ray single crystal diffraction. The crystal structural analyses show that the complex belongs to triclinic system, space group is P1 with a=1. 07360(19) nm, b=1. 2491(2) nm, c=1. 8976(3) nm, α=83. 809(2)°, β=89. 595(2)°, γ=65. 708(2)°, V=2. 3039(7) nm3, Z=2. The complex molecular consists of three different coordinated zinc ions which are connected by intramolecular hydrogen bonds into a total molecular, and 2D network structure is further formed by intermolecular hydrogen bonds. The catalytic performance of the metal complex in Henry reaction was studied, and the optimum catalytic conditions were obtained. The results show that the complex exhibits a high catalytic performance with 9%( molar fraction) of catalyst loading, methanol as solvent and reaction at room temperature for 20 h.