CAJ | 학술논문

合成含有大量端羟基的超支化聚酰胺酯，用硅烷偶联剂KH560对其封端改性制成超支化界面剂，用超支化界面剂处理涤棉帆布带芯，制成聚氯乙烯（PVC）阻燃输送带。研究超支化界面剂对PVC输送带粘合性能的影响。结果表明：随着超支化界面剂浓度增大，输送带覆盖层与帆布带芯的层间粘合强度提高；第3代超支化界面剂（AB2型单体与核分子三羟甲基丙烷以物质的量比21∶1合成第3代超支化聚酰胺酯，第3代超支化聚酰胺酯与硅烷偶联剂KH560以物质的量比24∶1合成第3代超支化界面剂），其浓度为0.003 mol·L-1时输送带的层间粘合强度最高；使用超支化界面剂的输送带耐高温性能良好，在100℃时层间粘合强度保持率仍能达到75%以上；超支化界面剂的成本比硅烷偶联剂低，推荐浓度为2%～2.5%，超支化界面剂具有良好的经济性和工业化应用前景。
합성함유대량단간기적초지화취선알지，용규완우련제KH560대기봉단개성제성초지화계면제，용초지화계면제처리조면범포대심，제성취록을희（PVC）조연수송대。연구초지화계면제대PVC수송대점합성능적영향。결과표명：수착초지화계면제농도증대，수송대복개층여범포대심적층간점합강도제고；제3대초지화계면제（AB2형단체여핵분자삼간갑기병완이물질적량비21∶1합성제3대초지화취선알지，제3대초지화취선알지여규완우련제KH560이물질적량비24∶1합성제3대초지화계면제），기농도위0.003 mol·L-1시수송대적층간점합강도최고；사용초지화계면제적수송대내고온성능량호，재100℃시층간점합강도보지솔잉능체도75%이상；초지화계면제적성본비규완우련제저，추천농도위2%～2.5%，초지화계면제구유량호적경제성화공업화응용전경。
The hyperbranched polyamide ester with large amount of hydroxyl end groups was prepared and then modiifed with silane coupling agent KH560. The product was a hyperbranched interface agent and applied in the treatment of polyester-cotton canvas of flame retardant PVC conveyor belt. The test results showed that the adhesion strength between cover rubber and polyester-cotton canvas was improved by using the interface agent. Typically, the 3rd generation hyperbranched polyamide ester was prepared by using AB2 monomer and trimethylolpropane as the core, at the molar ratio of 21∶1. Correspondingly, the 3rd generation interface agent was obtained by using the 3rd generation hyperbranched polyamide ester and KH560 at the molar ratio of 24∶1. It was found that when the concentration of the 3rd generation interface agent in the treatment was 0.003 mol·L-1, the maximum adhesion strength between cover rubber and polyester-cotton canvas was achieved. The high temperature performance of the belt with the hyperbranched interface agent was excellent and the adhesion strength at 100℃was still able to keep more than 75%. The cost of the hyperbranched interface agent was lower than the silane coupling agent, and the recommended concentration was 2%~2.5%.