CAJ | 학술논문

以聚（乙烯-alt-马来酸）的苯乙胺衍生物与聚烯丙基胺盐酸盐为原料，通过层层自组装技术（LBL ）在色谱硅胶表面交替沉积得到聚电解质多层膜高效液相色谱（HPLC ）固定相；利用紫外光谱、红外光谱和元素分析研究了HPLC固定相的结构和组成。结果表明，聚电解质多层膜 HPLC固定相被成功构筑在硅胶颗粒表面；制备的多层膜固定相可方便地用于6种芳香烃类及4种烷基苯类物质的分离分析。本文的研究结果说明LBL技术在制备HPLC固定相方面具有一定的应用价值。
이취（을희-alt-마래산）적분을알연생물여취희병기알염산염위원료，통과층층자조장기술（LBL ）재색보규효표면교체침적득도취전해질다층막고효액상색보（HPLC ）고정상；이용자외광보、홍외광보화원소분석연구료HPLC고정상적결구화조성。결과표명，취전해질다층막 HPLC고정상피성공구축재규효과립표면；제비적다층막고정상가방편지용우6충방향경류급4충완기분류물질적분리분석。본문적연구결과설명LBL기술재제비HPLC고정상방면구유일정적응용개치。
A novel high performance liquid chromatograph (HPLC) stationary phase was fabri-cated on the surface of spherical silica v ia the alternate layer-by-layer (LBL ) self-assmbly of poly (allylamine hydrochloride ) and α-phenylethylamine derivative of poly (ethylene-alt-maleic acid) .The structure and composition of as-obtained multilayer HPLC stationary phase were analyzed by ultraviolet-visible light spectrophotometry ,infrared spectrometry ,and elemental analysis .Results indicate that polyelectrolyte multilayer film is successfully incorporated onto the surface of silica gel particulates .Besides ,as-prepared multilayer HPLC stationary phase can be readily used to separate and analyze six kinds of aromatic hydrocarbons and four kinds of alkyl benzene ,which demonstrates that LBL technique exhibits promising potential in prepar-ing HPLC stationary phase .