中国有色金属学报
中國有色金屬學報
중국유색금속학보
THE CHINESE JOURNAL OF NONFERROUS METALS
2014年
5期
1319-1326
,共8页
刘发兰%赵树森%高文焱%周春阳%王奕博%林学春
劉髮蘭%趙樹森%高文焱%週春暘%王奕博%林學春
류발란%조수삼%고문염%주춘양%왕혁박%림학춘
WC涂层%激光熔覆%显微组织%显微硬度
WC塗層%激光鎔覆%顯微組織%顯微硬度
WC도층%격광용복%현미조직%현미경도
WC coating%laser cladding%microstructure%microhardness
在304不锈钢(304SS)和Q235碳钢上分别熔覆Ni60A及Ni60A-WC金属粉末,以及添加Cr和Cr 3 C 2的涂层,利用光学显微镜(OM)、扫描电镜(SEM)、能谱仪(EDS)分析涂层的宏观形貌、微观组织和元素分布,用显微硬度计对涂层的硬度进行测试分析。结果表明:基材中元素成分的不同会导致涂层气孔和裂纹的差异,Ni、Cr元素含量高的304SS上的涂层气孔和裂纹数明显比Q235碳钢上的少;基材的导热性能对涂层的稀释率与性能具有明显影响,导热性能差的304SS稀释率大,WC颗粒分解多,涂层组织粗大;由于Q235导热性能好,冷却速率高,导致涂层硬度高,Ni60A+40%WC涂层平均硬度高达1000HV 0.2。此外,Cr和Cr 3 C 2的加入能有效防止涂层气孔的产生。
在304不鏽鋼(304SS)和Q235碳鋼上分彆鎔覆Ni60A及Ni60A-WC金屬粉末,以及添加Cr和Cr 3 C 2的塗層,利用光學顯微鏡(OM)、掃描電鏡(SEM)、能譜儀(EDS)分析塗層的宏觀形貌、微觀組織和元素分佈,用顯微硬度計對塗層的硬度進行測試分析。結果錶明:基材中元素成分的不同會導緻塗層氣孔和裂紋的差異,Ni、Cr元素含量高的304SS上的塗層氣孔和裂紋數明顯比Q235碳鋼上的少;基材的導熱性能對塗層的稀釋率與性能具有明顯影響,導熱性能差的304SS稀釋率大,WC顆粒分解多,塗層組織粗大;由于Q235導熱性能好,冷卻速率高,導緻塗層硬度高,Ni60A+40%WC塗層平均硬度高達1000HV 0.2。此外,Cr和Cr 3 C 2的加入能有效防止塗層氣孔的產生。
재304불수강(304SS)화Q235탄강상분별용복Ni60A급Ni60A-WC금속분말,이급첨가Cr화Cr 3 C 2적도층,이용광학현미경(OM)、소묘전경(SEM)、능보의(EDS)분석도층적굉관형모、미관조직화원소분포,용현미경도계대도층적경도진행측시분석。결과표명:기재중원소성분적불동회도치도층기공화렬문적차이,Ni、Cr원소함량고적304SS상적도층기공화렬문수명현비Q235탄강상적소;기재적도열성능대도층적희석솔여성능구유명현영향,도열성능차적304SS희석솔대,WC과립분해다,도층조직조대;유우Q235도열성능호,냉각속솔고,도치도층경도고,Ni60A+40%WC도층평균경도고체1000HV 0.2。차외,Cr화Cr 3 C 2적가입능유효방지도층기공적산생。
Ni60A and Ni60A-WC laser cladding coatings were prepared on 304 stainless steel and Q235 carbon steel, respectively, as well as adding Cr and Cr3C2 coatings. The macroscopic morphology, microstructure and elemental distribution of the coatings were analyzed by optical microscopy (OM), scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS). The microhardness of the coatings were tested with microhardness tester. The results show that the element composition on the substrate can cause the differences of pores and cracks. The pores and cracks of the coatings on 304 stainless steel (with high contents of Ni and Cr elements) are significantly less than those of the the coatings on Q235 carbon steel. The thermal conductivity of the substrates have a significant impact on the dilution rate and performance of the coatings. Because of poor thermal conductivity, the coatings on 304 stainless steel have high dilution rate, more WC particles decompose and then coarsen the microstructure. The average hardness of Ni60A+40%WC coating on Q235 substrate up to 1000HV 0.2 attributes to its good thermal conductivity and high cooling rate. Furthermore, pore free coatings adding with Cr and Cr3C2 are obtained.