CAJ | 학술논문

利用表面离子印迹技术制备铅离子印迹聚合物，通过红外光谱进行了表征，考察了铅离子印迹聚合物最佳吸附条件。结果表明： pH值3.5左右时，印迹聚合物对铅离子具有良好的吸附性，且吸附速度快，1mol/L盐酸即可解吸铅离子92%。在优化的试验条件下，静态吸附量22.7mg/g，是非印迹聚合物的2倍，最大富集倍数100，印迹聚合物具有较好的选择性，样品加标回收率在91.5%～102.8%，相对标准偏差为2.34%~5.65%，结果令人满意。
이용표면리자인적기술제비연리자인적취합물，통과홍외광보진행료표정，고찰료연리자인적취합물최가흡부조건。결과표명： pH치3.5좌우시，인적취합물대연리자구유량호적흡부성，차흡부속도쾌，1mol/L염산즉가해흡연리자92%。재우화적시험조건하，정태흡부량22.7mg/g，시비인적취합물적2배，최대부집배수100，인적취합물구유교호적선택성，양품가표회수솔재91.5%～102.8%，상대표준편차위2.34%~5.65%，결과령인만의。
L ead ion imprinted polymer was prepared with surface ionic imprinting , technology was character-ized through infrared spectroscopy. Besides, the optimum adsorption conditions of lead ion imprinted polymer were ex-amined. Results showed as follows: when pH was about 3.5, imprinted polymers had a favorable and fast adsorption to lead ion and 92%lead ion could be desorbed by 1mol/L hydrochloric acid. Under optimized experimental conditions, maximum saturated adsorbing capacity was 22.7mg/g, which was twice amount of non-imprinted polymers and maxi-mum concentration multiple was 100. Imprinted polymers had a prefer able selectivity. Adding standard recovery rate ranges was from 91.5%to 102.8%and the relative standard deviation was between 2.34% to 5.65%.These results were satisfactory.